Playing with the cavity size of exTTF-based self-assembled cages

被引:2
|
作者
Dekhtiarenko, Maksym [1 ,2 ]
Szaloki, Gyoergy [1 ]
Croue, Vincent [1 ]
Bou Zeid, Jennifer [1 ]
Canevet, David [1 ]
Allain, Magali [1 ]
Carre, Vincent [3 ]
Aubriet, Frederic [3 ]
Voitenko, Zoia [2 ]
Salle, Marc [1 ]
Goeb, Sebastien [1 ]
机构
[1] Univ Angers, CNRS, MOLTECH Anjou, F-49000 Angers, France
[2] Taras Shevchenko Natl Univ Kyiv, 64-13 Volodymyrska St, UA-01033 Kiev, Ukraine
[3] Univ Lorraine, LCP A2MC, F-57000 Metz, France
关键词
COORDINATION CAGES; GUEST; COMPLEXES; DESIGN; HOST; METALLOMACROCYCLES; METALLACYCLES; CONSTRUCTION; PRINCIPLES; SEPARATION;
D O I
10.1039/d3qo00214d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
M4L2 metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.
引用
收藏
页码:1803 / 1810
页数:8
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