Kinetics of the Diels-Alder Reaction of 2,5-Dimethylfuran with N-Phenylmaleimide: High Hydrostatic Pressure, Temperature, and Solvent Effects

被引：0

作者：

Kornilov, D. A. ^{[1
,2
]}

机构：

[1] Ufa Univ Sci & Technol, Fac Chem, Ufa 450076, Russia

[2] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan 420008, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 59卷 / 09期

关键词：

activation volume; reaction volume; high hydrostatic pressure; 2,5-dimethylfuran; N-phenylmale-imide; Diels-Alder reaction; ANTIMICROBIAL ACTIVITY; REACTION VOLUMES; BENZOFURAN; DERIVATIVES; ACTIVATION; ENTROPY; PINENE;

D O I：

10.1134/S1070428023090117

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rate constants of the Diels-Alder reaction of 2,5-dimethylfuran (1) with N-phenylmaleimide (2) have been determined in five solvents in the temperature range from 25 to 45(degrees)C and pressure range from 1 to 1000 bar. The enthalpies, entropies, Gibbs free energies of activation, and volume parameters of this reaction have been calculated. The equilibrium constants for the reaction of 1 and 2 in benzene have been determined in the temperature range from 25 to 55(degrees)C, and the enthalpy and entropy of the reaction have been calculated.

引用

页码：1543 / 1547

页数：5

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