Comparative analysis of hydrogen, methane and nitrogen relative permeability: Implications for Underground Hydrogen Storage

Underground Hydrogen Storage (UHS) is an emerging technology which aims to store terawatt-scale energy in the subsurface to alleviate daily and seasonal fluctuations in the ever-increasing renewable energy market. Depleted gas reservoirs and aquifers will be the main targets of storage which requires an understanding of the interaction between formation or cushion gas with native brine. A comprehensive comparison of the petrophysical and two-phase flow properties of the hydrogen-water, methane-water and nitrogen-water systems at insitu conditions is the focus of our work. We conduct steady-state relative permeability experiments at 2.13 MPa and 298 K using identical capillary numbers of Nc = 2.92 x 10-7 for all three systems. The saturation and in-situ contact angles are determined with segmentation of 3D micro-CT images. The contact angle of each system is almost identical at the irreducible water saturation, Swi, 44 degrees, 46 degrees, 45 degrees, respectively, as is the interfacial tension of 72.0, 71.5 and 71mN/m, respectively. The capillary pressure-saturation relationships for each system have a maximum difference of 3.8 % which leads to approximately equivalent relative permeability in the Bentheimer sandstone core. The end-point relative permeabilities are k0 rg = 0.049, k0 rg = 0.045 and k0 rg = 0.062 at irreducible water saturations of Swi = 0.24, Swi = 0.25 and Swi = 0.23, respectively. All three gases demonstrate equivalent flow properties which indicates that both nitrogen and methane are suitable analogue gases for laboratory multiphase flow experiments and cushion gas to improve safety and the economics of commercial UHS projects. The results enable history matched depleted gas reservoir performance to be used as a guide for UHS.