Characterization of partially Ni substituted manganese hexacyanoferrate cathode material

被引：3
|
作者：
Maisuradze, Mariam [1 ]
Li, Min [1 ]
Aquilanti, Giuliana [2 ]
Plaisier, Jasper [2 ]
Giorgetti, Marco [1 ]
机构：
[1] Univ Bologna, Dept Ind Chem Toso Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy
[2] Elettra Sincrotrone Trieste, Ss 14,Km 163-5, I-34149 Trieste, Italy
来源：
MATERIALS LETTERS | 2023年 / 330卷
关键词：
Manganese hexacyanoferrate; X-ray absorption; X-ray diffraction; Cathode Material; RAY-ABSORPTION SPECTROSCOPY; PRUSSIAN BLUE; ION;
D O I：
10.1016/j.matlet.2022.133259
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Manganese Hexacyanoferrate (MnHCF) and partially nickel substituted MnHCF were synthesized by simple coprecipitation method. The water content and chemical formula were obtained by TGA and MP-AES measurements, functional groups by FT-IR analysis, the crystal structure by PXRD and a local geometry by XAS-EXAFS spectroscopy. With the addition of nickel, vacancies and water content increased inside the sample. Crystal structure has changed from monoclinic to cubic. Ni disturbed the local structure of Mn, site, however, almost no change was observed in Fe site.
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页数：3
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