Dually Sulphophilic Chromium Boride Nanocatalyst Boosting Sulfur Conversion Kinetics Toward High-Performance Lithium-Sulfur Batteries

The sluggish kinetics of sulfur conversions have long been hindering the implementation of fast and efficient sulfur electrochemistry in lithium-sulfur (Li-S) batteries. In this regard, herein the unique chromium boride (CrB) is developed via a well-confined mild-temperature thermal reaction to serve as an advanced sulfur electrocatalyst. Its interstitial-alloy nature features excellent conductivity, while the nano-lamination architecture affords abundant active sites for host-guest interactions. More importantly, the CrB nanocatalyst demonstrates a dual sulphophilicity with simultaneous CrS and BS bondage for establishing strong interactions with the intermediate polysulfides. As a result, significant stabilization and promotion of sulfur redox behavior can be achieved, enabling an excellent Li-S cell cyclability with a minimum capacity fading rate of 0.0176% per cycle over 2000 cycles and a favorable rate capability up to 7 C. Additionally, a high areal capacity of 5.2 mAh cm-2, and decent cycling and rate performances are still attainable under high sulfur loading and low electrolyte dosage. This work offers a facile approach and instructive insights into metal boride sulfur electrocatalyst, holding a good promise for pursuing high-efficiency sulfur electrochemistry and high-performance Li-S batteries. Chromium boride is developed for the first time as sulfur electrocatalyst, which imposes a unique dual-sulphophilic mechanism via p-d and p-p hybridizations with the polysulfide intermediates. As a result, fast and durable sulfur electrochemistry is realized, contributing to excellent cyclability, rate capability, and high-loading performances of Li-S batteries.image