Asymmetric total syntheses of sarbracholide and shizukaol B

被引：2
|
作者：
Huang, Ganxing [1 ]
Huang, Zhengsong [1 ]
Ma, Xianjian [1 ]
Feng, Zhihu [1 ]
Yuan, Fengxia [1 ]
Qin, Song [1 ]
Fu, Shaomin [1 ]
Liu, Bo [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 14期
关键词：
LINDENANE SESQUITERPENOID DIMERS; CHLORANTHACEAE PLANTS; CHEMICAL-CONSTITUENTS; INTRAMOLECULAR CYCLOPROPANATION; A-C; CHLORAHOLOLIDES; BLOCKERS; CONCISE; POTENT; DIELS;
D O I：
10.1039/d3qo00643c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Asymmetric syntheses of lindenane sesquiterpenoid [4 + 2] head-to-back dimers, namely sarbracholide and shizukaol B, are presented herein. In this synthesis, an MTBD-mediated one-pot Z-type elimination/lactonization was performed to install an alpha,beta-unsaturated lactone, while a biomimetic [4 + 2] dimerization between a triene and dienophile was carried out to establish the dimers.
引用
收藏
页码：3591 / 3597
页数：7
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