Divalent metal complexes of N,O- and N,N-bidentate imidazo[1,5-a] pyridine ligands: Synthesis, crystal structures, and photophysical properties

被引：0

作者：

Imada, Yasushi ^{[1
]}

Mukai, Shoma ^{[1
]}

Tahara, Koki ^{[1
]}

Kozai, Natsumi ^{[1
]}

Itaya, Masami ^{[1
]}

Yoshida, Yasushi ^{[2
]}

Ueta, Shoko ^{[1
]}

Arakawa, Yukihiro ^{[1
]}

Minagawa, Keiji ^{[1
]}

Yagishita, Fumitoshi ^{[1
,3
]}

机构：

[1] Tokushima Univ, Dept Appl Chem, 2-1 Minamijosanjima, Tokushima 7708506, Japan

[2] Chiba Univ, Grad Sch Engn, Dept Appl Chem & Biotechnol, 1-33 Yayoi cho, Inage ku, Chiba 2638522, Japan

[3] Tokushima Univ, Inst Postled Photon, 2-1 Minamijosanjima, Tokushima 7708506, Japan

来源：

INORGANICA CHIMICA ACTA | 2023年 / 555卷

关键词：

N; O-Ligand; N-Ligand; Imidazo[1; 5-a]pyridines; Crystal structures; CATALYTIC-ACTIVITY; ORGANIC FRAMEWORKS; COUPLING REACTIONS; HIGHLY EFFICIENT; EMISSION; PHOTOSENSITIZERS; TRANSFORMATIONS; POLYMERIZATION; PROBE; ANGLE;

D O I：

10.1016/j.ica.2023.121584

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two types of imidazo[1,5-a]pyridine ligands have been reacted with divalent metals (Pd and Zn) to prepare the corresponding complexes. Single crystallographic analyses revealed that 1-(o-hydroxyphenyl)imidazo[1,5-a] pyridine and 3,3 & PRIME;-biimidazo[1,5-a]pyridine act as N,O-bidentate ligand for homoleptic palladium complex and N, N-bidentate ligand for zinc dichloride complex, respectively.

引用

页数：5

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