The characteristics of ultrafine gold minerals in gold concentrate with a high copper content produced by a large gold mining company in Shandong Province were determined via chemical composition analysis, phase analysis, and mineral liberation analysis. The results showed that the concentrate contained 48.13 g/t gold, which was mainly in the form of native gold and electrum. Regarding the gold mineral particles, 57.65% were completely liberated and 35.75% were associated with chalcopyrite and pyrite. The remainder mainly comprised wrapped intergrowths. The cumulative distributions of native gold and electrum fractions with diameters of less than 75 mu m were 82.55% and 90.15%, respectively. Enhanced Cu-S bulk flotation, and then, Cu-S separation from the raw material were proposed to effectively enrich the gold minerals and decrease the treatment throughput during the leaching operation. The optimized conditions yielded a concentrate with a high copper content (3.89% Cu and 545.62 g/t Au contents, and 83.15% Cu and 77.54% Au recoveries) and a concentrate with a high sulfur content (0.059% Cu and 15.03 g/t Au contents, and 83.15% Cu and 21.28% Au recoveries). The capacity of the subsequent leaching process was reduced by 25%. Ammonia pretreatment was introduced to decrease the adverse effect of copper on cyanidation leaching for the copper concentrate. Under the optimized leaching conditions, gold dissolution reached 99.76%, which was approximately 4% higher than that obtained via direct leaching. The NaCN consumption decreased over 10 kg/t. These results could serve as a valuable reference for the economic and green utilization of gold resources from concentrate with a high copper content.
