Local Electrochemical Corrosion of 6061 Aluminum Alloy with Nano-SiO2/MAO Composite Coating

被引:7
|
作者
Zhao, Jie [1 ]
Zhang, Hongwei [1 ]
Yang, Xiaoyu [2 ]
Gu, Yanhong [2 ]
Liu, Yida [2 ]
机构
[1] Beijing Inst Petrochem Technol, Sch Safety Engn, Beijing 102617, Peoples R China
[2] Beijing Inst Petrochem Technol, Sch Mech Engn, Beijing 102617, Peoples R China
关键词
6061 aluminum alloy; micro-arc oxidation; nano-SiO2; composite coating; local electrochemistry; MICRO-ARC OXIDATION; PLASMA ELECTROLYTIC OXIDATION; AL-ALLOY; BEHAVIOR; RESISTANCE; PERFORMANCE;
D O I
10.3390/ma16206721
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To improve the corrosion resistance of 6061 Al in electric vehicle battery packs, a composite coating of nano-SiO2/Micro-Arc oxidation (MAO) ceramic structure was prepared on its surface. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves (PDP) were used to evaluate the corrosion resistance of the specimens after 7 days immersion in a 3.5% NaCl solution. The corrosion resistance of the prefabricated coatings was measured via local electrochemical impedance spectroscopy (LEIS). Confocal microscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD) were used to characterize the microstructure and phase composition of the specimens. An energy dispersive spectrometer (EDS) was used to detect the elemental composition of the surface of the specimen. The results showed that the specimen with nano-SiO2/MAO composite coating had the least amount of micropores and superior corrosion resistance. The global electrochemical impedance of nano-SiO2/MAO composite coating was 1.1 times higher than that of the MAO coating and 8.4 times higher than that of the 6061 Al. When the coating was defective, the local electrochemical impedance of the nano-SiO2/MAO composite coating was still two times higher than that of the MAO coating. In the presence of scratches, the nano-SiO2/MAO composite coating still showed high corrosion resistance. The collapse corrosion mechanism of the nano-SiO2/MAO composite coating was proposed.
引用
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页数:20
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