Electron donor-acceptor complex enabled cascade reaction of unprotected o-anilide aryl chlorides for heterocycle synthesis

被引：6
|
作者：
Yang, Zhu-Sheng [1 ,2 ]
Tang, Wen-Xin [2 ,4 ]
Zhang, Bei-Bei [2 ]
Sun, De-Qun [4 ]
Chen, Kun-Quan [2 ]
Chen, Xiang-Yu [2 ,3 ]
机构：
[1] Guizhou Normal Univ, Sch Mat & Architectural Engn, Guiyang 550025, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
[3] Binzhou Inst Technol, Weiqiao UCAS Sci & Technol Pk, Binzhou 256606, Shandong, Peoples R China
[4] Southwest Univ Sci & Technol, Sch Life Sci & Engn, Mianyang 621010, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 05期
基金：
中国国家自然科学基金;
关键词：
HYDRATED ELECTRONS; LIGHT; REDUCTION;
D O I：
10.1039/d2qo01863b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An electron donor-acceptor (EDA) complex strategy that enabled photoactivation of unprotected o-anilide aryl chlorides has been reported. This EDA strategy provides a simple approach for the synthesis of several heterocycles. In this strategy, the toluene anion or tBuOK forms an EDA complex with aryl chlorides.
引用
收藏
页码：1219 / 1223
页数：5
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