Thianthrenium-Enabled Phosphorylation of Aryl C-H Bonds via Electron Donor-Acceptor Complex Photoactivation

被引：41

作者：

Xu, Hao ^{[1
]}

Li, Xufeng ^{[2
]}

Dong, Yuzheng ^{[1
]}

Ji, Shuangran ^{[1
]}

Zuo, Junze ^{[1
]}

Lv, Jian ^{[1
]}

Yang, Daoshan ^{[1
,3
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, MOE, Qingdao 266042, Peoples R China

[2] Zhejiang Wansheng Co Ltd, Linhai 317000, Zhejiang, Peoples R China

[3] Nanjing Forestry Univ, Natl Engn Res Ctr Low Carbon Proc & Utilizat Fores, Nanjing 210037, Peoples R China

来源：

ORGANIC LETTERS | 2023年 / 25卷 / 20期

基金：

中国国家自然科学基金;

关键词：

PHOTOREDOX CATALYSIS; FUNCTIONALIZATION; ARYLATION; SULFONYLATION; ALKYLATION; ARENES; SALTS; OXIDE;

D O I：

10.1021/acs.orglett.3c01303

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anefficient strategy for the preparation of aryl phosphonatesvia blue-light-promoted single electron transfer process of an EDAcomplex between phosphites and thianthrenium salts has been demonstrated.The corresponding substituted aryl phosphonates were obtained in goodto excellent yields, and the byproduct thianthrene can be recoveredand reused in quantity. This developed method realizes the constructionof aryl phosphonates through the indirect C-H functionalizationof arenes, which has potential application value in drug discoveryand development.

引用

页码：3784 / 3789

页数：6

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