Experimental Mechanism for Enhancing Oil Recovery by Spontaneous Imbibition with Surfactants in a Tight Sandstone Oil Reservoir

This study aims to investigate the mechanism behind surfactant enhanced oil recovery under reservoir conditions through experiments on spontaneous imbibition with surfactants. The tight sandstone samples are characterized using cast thin section (CTS), high-pressure mercury intrusion (HPMI), and nuclear magnetic resonance (NMR) to determine their clay mineral composition, pore size distribution, and fluid distribution. Spontaneous imbibition experiments are then conducted using formation water and surfactant solutions as imbibition liquids, with three different types of surfactants-dodecylbenzene sulfonate (DBS), sodium dodecyl sulfate (SDS), and ammonium bromide-at two different concentrations, each to examine the effect of surfactant type. Additionally, the interfacial tension (IFT) between crude oil and different imbibition solutions is measured, and the contact angles of an oil droplet on the core surface in air, formation water, distilled water, and surfactant solution are determined. Finally, the effects of IFT, rock wettability, formation water salinity, and core permeability on final oil recovery by spontaneous imbibition are analyzed. The results indicate that surfactant-assisted spontaneous imbibition primarily operates through IFT reduction, wettability alteration, and emulsification of crude oil. However, ultralow IFT may lead to low ultimate oil recovery. To increase the ultimate oil recovery of spontaneous imbibition, reducing the salinity of the surfactant solution and creating microfractures can be effective strategies.