Dual metal site-mediated efficient C-N coupling toward electrochemical urea synthesis

被引：49
|
作者：
Paul, Sourav [1 ]
Sarkar, Sougata [1 ]
Adalder, Ashadul [1 ]
Banerjee, Amitava [2 ]
Ghorai, Uttam Kumar [1 ]
机构：
[1] Ramakrishna Mission Vidyamandira, Swami Vivekananda Res Ctr, Dept Ind Chem & Appl Chem, Howrah 711202, West Bengal, India
[2] Indian Inst Technol Jodhpur, Dept Met & Mat Engn, Jodhpur 342030, Rajasthan, India
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2023年 / 11卷 / 25期
关键词：
MOS2; NANOTUBES; AMMONIA; CARBON; CO2;
D O I：
10.1039/d3ta01011b
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electrochemical urea synthesis is a promising technology for carbon utilization. Herein, we report a CoPc-MoS2 system for promoting urea synthesis by a C-N coupling reaction. Dual metal sites mediate N-2 activation and CO2 adsorption insertion to produce a urea yield of 175.6 mu g h(-1) mg(cat)(-1) at -0.7 V vs. RHE.
引用
收藏
页码：13249 / 13254
页数：6
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