A Chemical Safety Assessment of Lyocell-Based Activated Carbon Fiber with a High Surface Area through the Evaluation of HCl Gas Adsorption and Electrochemical Properties
被引:2
|
作者:
Kim, Jong Gu
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机构:
Korea Res Inst Biosci & Biotechnol, Natl Res Safety Headquarters, Cheongju 28116, South KoreaKorea Res Inst Biosci & Biotechnol, Natl Res Safety Headquarters, Cheongju 28116, South Korea
Kim, Jong Gu
[1
]
Bai, Byong Chol
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机构:
Daejin Univ, Div Energy Engn, Pochon 11159, South KoreaKorea Res Inst Biosci & Biotechnol, Natl Res Safety Headquarters, Cheongju 28116, South Korea
Bai, Byong Chol
[2
]
机构:
[1] Korea Res Inst Biosci & Biotechnol, Natl Res Safety Headquarters, Cheongju 28116, South Korea
[2] Daejin Univ, Div Energy Engn, Pochon 11159, South Korea
chemical safety assessment;
activated carbon fiber;
HCl gas;
adsorption;
gas sensing;
AIR-POLLUTION;
HEALTH;
REMOVAL;
D O I:
10.3390/separations11030079
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
This study investigates lyocell-based activated carbon fibers (ACFs) for their suitability in adsorbing and electrochemically detecting toxic HCl gas. ACFs were prepared via steam activation, varying temperature (800-900 degrees C) and time (40-240 min) to assess their adsorption and sensing capabilities. The adjustment of activation temperature and reaction time aimed to regulate the uniformity of the pore structure and pore size of the active reaction area, as well as the number of reaction sites in the ACFs. Optimal ACFs were achieved at 900 degrees C for 50 min, exhibiting the highest specific surface area (1403 m2/g) and total pore volume (0.66 cm3/g). Longer reaction times resulted in pore formation and disorder, reducing mechanical strength. The ACFs prepared under optimal conditions demonstrated a rapid increase in resistance during sensor measurement, indicating a significant sensitivity to HCl gas. These findings suggest the potential of ACFs for efficient HCl gas adsorption (1626.20 mg/g) and highlight the importance of activation parameters in tailoring their properties for practical applications.
机构:
Department of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan MalaysiaDepartment of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan Malaysia
Alfarooq O.Basheer
Marlia M.Hanafiah
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机构:
Department of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan Malaysia
Centre for Tropical Climate Change System, Institute of Climate Change, Universiti Kebangsaan MalaysiaDepartment of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan Malaysia
Marlia M.Hanafiah
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机构:
Mohammed Abdulhakim Alsaadi
Y.Al-Douri
论文数: 0引用数: 0
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机构:
Nanotechnology and Catalysis Research Center (NANOCAT), University of Malaya
University Research Center, Cihan University Sulaimaniya
Department of Mechatronics Engineering, Faculty of Engineering and Natural Sciences, Bahcesehir UniversityDepartment of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan Malaysia
Y.Al-Douri
Abbas A.Al-Raad
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机构:
Department of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan MalaysiaDepartment of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan Malaysia
机构:
Univ Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia
Basheer, Alfarooq O.
Hanafiah, Marlia M.
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机构:
Univ Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia
Univ Kebangsaan Malaysia, Ctr Trop Climate Change Syst, Inst Climate Change, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia
Hanafiah, Marlia M.
Alsaadi, Mohammed Abdulhakim
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机构:
Univ Malaya, Nanotechnol & Catalysis Res Ctr NANOCAT, Kuala Lumpur 50603, Malaysia
Univ Nizwa, Natl Chair Mat Sci & Met, Nizawa 611, OmanUniv Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia
Alsaadi, Mohammed Abdulhakim
Al-Douri, Y.
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机构:
Univ Malaya, Nanotechnol & Catalysis Res Ctr NANOCAT, Kuala Lumpur 50603, Malaysia
Cihan Univ Sulaimaniya, Univ Res Ctr, Sulaymaniyah 46002, Iraq
Bahcesehir Univ, Fac Engn & Nat Sci, Dept Mechatron Engn, TR-34349 Istanbul, TurkeyUniv Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia
Al-Douri, Y.
Al-Raad, Abbas A.
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h-index: 0
机构:
Univ Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, MalaysiaUniv Kebangsaan Malaysia, Dept Earth Sci & Environm, Fac Sci & Technol, Bangi 43600, Selangor, Malaysia
Al-Raad, Abbas A.
CHINESE JOURNAL OF CHEMICAL ENGINEERING,
2021,
32
: 472
-
484
机构:
Kyungpook Natl Univ, Coll Engn, Dept Text Syst Engn, Daegu 41566, South KoreaKyungpook Natl Univ, Coll Engn, Dept Text Syst Engn, Daegu 41566, South Korea
Ahn, Taemin
Kwon, Woong
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机构:
Kyungpook Natl Univ, Coll Engn, Dept Text Syst Engn, Daegu 41566, South KoreaKyungpook Natl Univ, Coll Engn, Dept Text Syst Engn, Daegu 41566, South Korea
Kwon, Woong
Bai, Byong Chol
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机构:
Daejin Univ, Div Energy Engn, 1007 Hoguk Rd, Pocheon Si 487711, South KoreaKyungpook Natl Univ, Coll Engn, Dept Text Syst Engn, Daegu 41566, South Korea
机构:
China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R ChinaChina Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
Wang, Qianyu
Fagbohun, Emmanuel Oluwaseyi
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机构:
Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
Toronto Metropolitan Univ, Dept Chem & Biol, Lab Nanomat & Mol Plasmon, 350 Victoria St, Toronto, ON M5B 2K3, CanadaChina Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
Fagbohun, Emmanuel Oluwaseyi
Zhu, Houkun
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R ChinaChina Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
Zhu, Houkun
Hussain, Abid
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R ChinaChina Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
Hussain, Abid
Wang, Fang
论文数: 0引用数: 0
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机构:
Beijing Technol & Business Univ, Sch Ecol & Environm, Beijing 100048, Peoples R ChinaChina Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
Wang, Fang
Cui, Yanbin
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机构:
Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R ChinaChina Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
机构:
Univ Teknol MARA, Fac Sci Appl, Coal & Biomass Energy Res Grp, Shah Alam 40450, Selangor, MalaysiaUniv Teknol MARA, Fac Sci Appl, Coal & Biomass Energy Res Grp, Shah Alam 40450, Selangor, Malaysia
Jawad, Ali H.
Rashid, Ramlah Abd
论文数: 0引用数: 0
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机构:
Univ Teknol MARA, Fac Sci Appl, Coal & Biomass Energy Res Grp, Shah Alam 40450, Selangor, MalaysiaUniv Teknol MARA, Fac Sci Appl, Coal & Biomass Energy Res Grp, Shah Alam 40450, Selangor, Malaysia
Rashid, Ramlah Abd
Ismail, Khudzir
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机构:
Univ Teknol MARA, Fac Sci Appl, Coal & Biomass Energy Res Grp, Shah Alam 40450, Selangor, MalaysiaUniv Teknol MARA, Fac Sci Appl, Coal & Biomass Energy Res Grp, Shah Alam 40450, Selangor, Malaysia
Ismail, Khudzir
Sabar, S.
论文数: 0引用数: 0
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机构:
Univ Sains Malaysia, Sch Distance Educ, Chem Sect, Minden 11800, Penang, MalaysiaUniv Teknol MARA, Fac Sci Appl, Coal & Biomass Energy Res Grp, Shah Alam 40450, Selangor, Malaysia