Regulation Mechanism of Ash Fusion of Iron-Rich Coal in Xinjiang with Different Additives

被引:0
|
作者
Lv, Junxin [1 ,2 ]
Zhang, Jiansheng [1 ]
Wang, Yonggang [2 ]
Lin, Xiongchao [2 ]
Liao, Changlin [1 ]
Liu, Xianghui [3 ]
机构
[1] Tsinghua Univ, Dept Energy & Power Engn, Beijing 100084, Peoples R China
[2] China Univ Min & Technol Beijing, Sch Chem & Environm Engn, Beijing 100083, Peoples R China
[3] China Energy Longyuan Environm Protect Co Ltd, Beijing, Peoples R China
来源
CHEMISTRYSELECT | 2024年 / 9卷 / 05期
基金
中国国家自然科学基金;
关键词
additives; ash fusion characteristics; coal blending; iron-rich coal; regulation mechanism; SLAG; BEHAVIOR; GASIFIER;
D O I
10.1002/slct.202303627
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To realize the high-efficiency utilization of iron-rich coal (ZC), it is necessary to conduct in-depth research on its ash fusion characteristics and regulation mechanism. In this paper, the fusion temperature test of ZC coal ash was first carried out in a weak reducing atmosphere, and diatomite (GZT) and Naomaohu high-calcium coal (NMH) were selected as additives. The results show that the four characteristic temperatures of ZC coal ash are all low under weak reducing conditions. The addition of NMH ash lowered the fusion temperature of ZC coal ash, while the GZT ash increased the fusion temperature to varying degrees. When the addition ratio of NMH ash is less than 40 %, the effect of increasing the difference between the deformation temperature and flow temperature of ZC coal ash is still positive. The addition of NMH ash made the slag system generate a high content of calcium-magnesium feldspar and calcium-iron feldspar, decreasing the fusion temperature of the blended coal ash. The addition of GZT ash increased the content of SiO2 in the slag system and promoted the increase of the iron-pyroxene content, and the formation of the iron-aluminum pyroxene and cordierite mineral phases, thereby increasing the coal ash fusion temperature. Using iron-rich coal as raw material, its melting characteristics under weak reducing conditions were studied. Diatomaceous earth ash and Naomaohu ash were used to regulate the chemical composition, and their influencing mechanism on the ash melting characteristics was obtained. Finally, we provide suggestions for the best additions and provide guidance for efficient use of resources. image
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页数:10
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