Metal nitrides, the Mars-van Krevelen mechanism and heterogeneously catalysed ammonia synthesis

被引：28
|
作者：
Daisley, A. [1 ]
Hargreaves, J. S. J. [1 ]
机构：
[1] Univ Glasgow, Sch Chem, Joseph Black Bldg, Glasgow G12 8QQ, Scotland
来源：
CATALYSIS TODAY | 2023年 / 423卷
基金：
英国工程与自然科学研究理事会;
关键词：
Nitrogen; Ammonia; Looping; Nitride; Mars-van Krevelen; NITROGEN ACTIVATION; MOLYBDENUM CARBIDE; EXCHANGE-REACTIONS; MAGNESIUM NITRIDE; CONVENIENT SOURCE; LATTICE NITROGEN; VANADIUM NITRIDE; URANIUM NITRIDE; COBALT; OXIDATION;
D O I：
10.1016/j.cattod.2022.08.016
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Whilst the Mars-van Krevelen mechanism is well established for metal oxide catalysed oxidation reactions, it has been much less studied in the case of nitrogen based reactions catalysed by metal nitrides. In this overview, some of the recent literature in relation to the possible operation of the Mars- van Krevelen mechanism for ammonia synthesis catalysed by metal nitrides is presented, along with some of the literature relating to the synthesis of ammonia via chemical looping approaches.
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页数：8
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