Organo-Metallic Palladium Complexes used for CO2 Storage and Environmental Remediation

被引:1
|
作者
Mahmood, Zinah N. [1 ]
Alias, Mahasin [1 ]
Yousif, Emad [2 ]
Baqer, Shaymaa R. [1 ]
Kadhom, Mohammed [3 ]
Ahmed, Dina S. [4 ]
Ahmed, Ahmed [5 ]
Husain, Amani A. [5 ]
Yusop, Rahimi M. [6 ]
Jawad, Ali H. [7 ]
机构
[1] Univ Baghdad, Coll Sci Women, Dept Chem, Baghdad, Iraq
[2] Al Nahrain Univ, Coll Sci, Dept Chem, Baghdad, Iraq
[3] Al Karkh Univ Sci, Coll Energy & Environm Sci, Dept Environm Sci, Baghdad, Iraq
[4] Al Mansour Univ Coll, Dept Med Instrumentat Engn, Baghdad, Iraq
[5] Al Mustansiriyah Univ, Coll Sci, Polymer Res Unit, Baghdad, Iraq
[6] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Bangi, Selangor, Malaysia
[7] Univ Teknol MARA, Fac Appl Sci, Shah Alam 40450, Selangor, Malaysia
来源
POLLUTION | 2023年 / 9卷 / 02期
关键词
Sodium fusidate; Transition metal; Gas separation; Gas storage; Gases uptake; FUSIDIC ACID; GAS-STORAGE; ADSORPTION; CAPTURE;
D O I
10.22059/POLL.2022.348855.1632
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Gas storage is an important branch of technology that has many economic and envi-ronmental aspects. This technique could save gas to the need time and contribute to solving the CO2 and global warming problems. In this work, the structure and physico-chemical properties of the prepared palladium complex were characterized in the solid and solution states using spectroscopic techniques. These examination methods include ultraviolet-visible (UV-Vis), Fourier transform infrared (FTIR), metal and elemental analyses, and measurements of magnetic susceptibility and conductivity at room tem-perature. Also, findings on the surface morphology and surface area were provided via Field emission scanning electron microscopy (FESEM) and Brunauer-Emmett- Teller (BET) techniques, respectively. High-pressure adsorption measurements were investigated by storing carbon dioxide, and the results proved that such materials own remarkable gas adsorption properties that make them a good option for gas separation and storage. Gases uptake at 323 K for the complexes leads to the highest CO2 uptake. The prepared material could pave the road for further exploitation of similar materials.
引用
收藏
页码:693 / 701
页数:9
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