Electrochemical N-Acylation of Sulfoximine with Hydroxamic Acid

被引：7

作者：

Huang, Wenxiu ^{[1
]}

Wang, Shoucai ^{[1
]}

Li, Mingzhe ^{[1
]}

Zhao, Longqiang ^{[1
]}

Peng, Mengyu ^{[1
]}

Kang, Chen ^{[1
]}

Jiang, Guangbin ^{[1
]}

Ji, Fanghua ^{[1
]}

机构：

[1] Guilin Univ Technol, Coll Chem & Bioengn, Guangxi Key Lab Electrochem & Magneto Chem Funct M, Guilin 541004, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 24期

基金：

中国国家自然科学基金;

关键词：

DIRECTING GROUP; AROYLATION; ARENES; OXIDATION; NITROXYL;

D O I：

10.1021/acs.joc.3c01903

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Despite the widespread applications of sulfoximines, green and efficient access to functionalized sulfoximines remains a challenge. By employing an electrochemical strategy, we describe an approach for the construction of N-aroylsulfoximines, which features a broad substrate scope, mild reaction conditions, safety on a gram scale, and no need for an external oxidant and transition metal catalysts.

引用

页码：17511 / 17520

页数：10

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