Modeling of the Interstellar Medium Optical Absorption Spectrum by Primitive Hybrid Molecules C24H30, C32H36, and C73H74

被引:0
|
作者
Chekulaev, M. S. [1 ]
Yastrebov, S. G. [1 ]
机构
[1] Ioffe Inst, St Petersburg, Russia
关键词
interaction of light with matter; new forms of carbon; interstellar medium;
D O I
10.1134/S1063785023900121
中图分类号
O59 [应用物理学];
学科分类号
摘要
Accounting for the different contributions of the aromatic rings, separated with sp(3) bonds, with ab initio method we constructed the hybrid cluster C73H74 which UV spectrum matches the most noticeable absorption band of 217.5 nm, known from astrophysical observations.
引用
收藏
页码:235 / 237
页数:3
相关论文
共 46 条
  • [31] A New Organic-Inorganic Hybrid Layered Molybdenum(V) Cobalt Phosphate Constructed from [H24(Mo16O32)Co16(PO4)24(OH)4(C5H4N)2(H2O)6]4- Wheels and 4,4′-Bipyridine Linkers
    Yu, Kai
    Zhou, Bai-Bin
    Yu, Yang
    Su, Zhan-Hua
    Yang, Guo-Yu
    INORGANIC CHEMISTRY, 2011, 50 (05) : 1862 - 1867
  • [32] X-ray diffraction, IR spectrum, optical properties, AIM, NBO, RDG, HS, Fukui function, biological and molecular docking analysis of a novel hybrid compound (C9H15N3)[CuCl4(H2O)]
    Gannouni, Afef
    Tahri, Wiem
    Roisnel, Thierry
    Riadh, Kefi
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1271
  • [33] Crystal structure of [1,4,8,11,15,18,22,25-octahydro-1,4:8,11:15,18:22,25-tetraethano-29H,31H-tetrabenzo[b,g,l,q]porphinato-κN29,κN30,κN31,κN32]copper(II) N-methylpyrrolidone trisolvate, Cu(C44H36N4) • 3C5H9NO
    Ararnaki, Shinji
    Sakai, Yoshimasa
    Yanagisawa, Hiroyuki
    Mizuguchi, Jin
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (01): : 69 - 71
  • [34] DFT modeling of band shifts and widths in the absorption spectrum of a 9-(diphenylamino)acridine/silica receptor center upon its interaction with gas-phase NH3, C2H5OH, and (CH3)2CO molecules
    Chashchikhin, Vladimir
    Rykova, Elena
    Scherbinin, Andrei
    Bagaturyants, Alexander
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2012, 112 (18) : 3110 - 3118
  • [35] Nanosecond and picosecond optical limiting properties of a square-planar complex C30H24N6O4S4Cu, CuL2 [HL = p-nitrobenzaldehyde S-benzyl dithiocarbazate]
    Zhu, XH
    Chen, XF
    Zhang, Y
    You, XZ
    Tan, WL
    Ji, W
    CHEMISTRY LETTERS, 1999, (11) : 1211 - 1212
  • [36] Synthesis, characterization and magnetic properties of [Mn30O24(OH)8(O2CCH2C(CH3)3)32(H2O)2(CH3NO2)4]:: the largest manganese carboxylate cluster
    Soler, M
    Rumberger, E
    Folting, K
    Hendrickson, DN
    Christou, G
    POLYHEDRON, 2001, 20 (11-14) : 1365 - 1369
  • [37] Cadmium-substitution promoted by nucleophilic attack of [Ni30C4(CO)34(CdX)2]6- (X = Cl, Br, I) carbido carbonyl clusters: Synthesis and characterization of the new [H7-nNi32C4(CO)36(CdX)]n- (X = Cl, Br, I; n=5, 6, 7) polycarbide
    Bernardi, Alessandro
    Femoni, Cristina
    Iapalucci, Maria Carmela
    Longoni, Giuliano
    Zacchini, Stefano
    INORGANICA CHIMICA ACTA, 2009, 362 (04) : 1239 - 1246
  • [38] A new Cu-halide organic-inorganic hybrid compound's synthesis, single-crystal X-ray diffraction, vibrational investigations, optical characteristics, and DFT calculation: (C12H20N2)CuCl4 Mater (vol 36, 106484, 2023)
    Aloui, Zouhaier
    Essid, Manel
    Bruno, Giuseppe
    Bella, Giovanni
    Santoro, Antonio
    Abid, Sonia
    MATERIALS TODAY COMMUNICATIONS, 2024, 38
  • [39] Crystal structure of 5,13,20,27-tetraazonia-32-thia-heptacyclo[25.2.2.22,5.213,16.217,20.17,11.122,25]nonatriaconta-2,4,7,9,11(37),13,15,17,19,22,24,27,29,30,33,35,38-heptadecaene tetrakis(hexafluorophosphate), C34H30F24N4P4S
    Scheytza, H
    Reissig, HU
    Rademacher, O
    Hahn, F
    Richter, J
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2000, 215 (01): : 75 - 76
  • [40] Crystal structure of 5,13,20,28-tetraazoniaheptacyclo-[26.2.2.2(2,5).2(13,16).2(17,20).1(7,11).1(22,26)]tetraconta-2,4,7,11(38),13,15,17,19,22,24,26(33),28,30,31,34, 35,39-octadecaen tetrakis(fluoroborate) monohydrate, (C36H32N4)(BF4)(4) (H2O)
    Scheytza, H
    Domschke, G
    Zahn, G
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (01): : 55 - 56