A Highly Robust and Conducting Ultramicroporous 3D Fe(II)-Based Metal-Organic Framework for Efficient Energy Storage

Exploitation of metal-organic framework (MOF) materials as active electrodes for energy storage or conversion is reasonably challenging owing to their poor robustness against various acidic/basic conditions and conventionally low electric conductivity. Keeping this in perspective, herein, a 3D ultramicroporous triazolate Fe-MOF (abbreviated as Fe-MET) is judiciously employed using cheap and commercially available starting materials. Fe-MET possesses ultra-stability against various chemical environments (pH-1 to pH-14 with varied organic solvents) and is highly electrically conductive (sigma = 0.19 S m-1) in one fell swoop. By taking advantage of the properties mentioned above, Fe-MET electrodes give prominence to electrochemical capacitor (EC) performance by delivering an astounding gravimetric (304 F g-1) and areal (181 mF cm-2) capacitance at 0.5 A g-1 current density with exceptionally high cycling stability. Implementation of Fe-MET as an exclusive (by not using any conductive additives) EC electrode in solid-state energy storage devices outperforms most of the reported MOF-based EC materials and even surpasses certain porous carbon and graphene materials, showcasing superior capabilities and great promise compared to various other alternatives as energy storage materials. A 3D redox-active, robust, electrically conductive, ultramicroporous triazolate Fe-MOF is employed as the exclusive electrode material for excellent gravimetric (304 F g-1) and areal (181 mF cm-2) capacitance coupled with high power and energy density even in durable solid-state asymmetric supercapacitor (ASC) devices with remarkable cycling stability, suppressing most of the reported MOF-based electrochemical capacitors, representing encouraging energy storage materials. image