The Chabauty-Kim method is a tool for finding the integral or rational points on varieties over number fields via certain transcendental p-adic analytic functions arising from certain Selmer schemes associated to the unipotent fundamental group of the variety. In this paper we establish several foundational results on the Chabauty-Kim method for curves over number fields. The two main ingredients in the proof of these results are an unlikely intersection result for zeroes of iterated integrals, and a careful analysis of the intersection of the Selmer scheme of the original curve with the unipotent Albanese variety of certain Q(p)-subvarieties of the restriction of scalars of the curve. The main theorem also gives a partial answer to a question of Siksek on Chabauty's method over number fields, and an explicit counterexample is given to the strong form of Siksek's question.