Hydrogenation of Olefins Catalyzed by a Cobalt(I) Hydride Complex with N-Heterocyclic Silylene

被引：4
|
作者：
Jia, Hongwei [1 ,2 ]
Du, Shaozhi [1 ,2 ]
Xu, Chuangchuang [1 ,2 ]
Mo, Zhenbo [1 ,2 ]
机构：
[1] Nankai Univ, Coll Chem, Frontiers Sci Ctr New Organ Matter, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Coll Chem, Frontiers Sci Ctr New Organ Matter, Tianjin 300071, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 26卷 / 18期
基金：
中国国家自然科学基金;
关键词：
cobalt; chemoselectivity; hydride; hydrogenation; N-heterocyclic silyene; ALPHA; BETA-UNSATURATED CARBOXYLIC-ACIDS; HIGHLY ENANTIOSELECTIVE HYDROGENATION; ASYMMETRIC HYDROGENATION; DIPHOSPHINE LIGANDS; ACTIVATION; DIHYDROGEN; ALKYL;
D O I：
10.1002/ejic.202300086
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Herein, we report the synthesis, characterization, and reactivity of the cobalt(I) complexes with an N-heterocyclic imino substituted silylene. The cobalt(I) hydride complex exhibits high catalytic efficiency and chemoselectivity as well as good functional group compatibility in the hydrogenation of olefins.
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页数：5
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