The Features of Action of Supported Pd Catalysts in the Suzuki-Miyaura Reaction

被引：6
|
作者：
Schmidt, A. F. [1 ]
Kurokhtina, A. A. [1 ]
Larina, E. V. [1 ]
Lagoda, N. A. [1 ]
Yavsin, D. A. [2 ]
Gurevich, S. A. [2 ]
Zelikman, V. M. [3 ]
Krotova, I. N. [3 ]
Rostovshchikova, T. N. [3 ]
Tarkhanova, I. G. [3 ]
机构：
[1] Irkutsk State Univ, Chem Dept, Irkutsk 664003, Russia
[2] RAS, Ioffe Inst, St Petersburg 194021, Russia
[3] Lomonosov Moscow State Univ, Fac Chem, Moscow 119991, Russia
来源：
KINETICS AND CATALYSIS | 2023年 / 64卷 / 01期
基金：
俄罗斯科学基金会;
关键词：
Suzuki-Miyaura reaction; palladium; heterogeneous catalysts; ionic liquids; kinetics; differential selectivity; mechanism; LASER ELECTRODISPERSION; HETEROGENEOUS CATALYSIS; COUPLING REACTIONS; ALUMINA; HYDRODECHLORINATION; COMPLEXES; PHASE; HECK;
D O I：
10.1134/S0023158423010081
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The paper presents the results of a comparative analysis of the differential selectivity of the Suzuki-Miyaura reaction with aryl bromides using various heterogeneous Pd precursors (PdCl42- and Pd-0) obtained by chemical modification and laser electrodispersion of palladium on heterogeneous supports of two types: SiO2 modified with an ionic liquid and gamma-Al2O3. The catalytic experiments were carried out under "ligand-free" conditions implying no additives of phosphines, amines, carbenes, or any other organic ligands for Pd stabilization. Changes in the differential selectivity of competing aryl bromides were observed while varying the nature and concentration of the Pd precursor, indicating a substantial contribution of true heterogeneous catalysis to the total conversion of substrates.
引用
收藏
页码：32 / 43
页数：12
相关论文
共 50 条
  • [41] Development of Titanium Dioxide-Supported Pd Catalysts for Ligand-Free Suzuki-Miyaura Coupling of Aryl Chlorides
    Yamada, Tsuyoshi
    Masuda, Hayato
    Park, Kwihwan
    Tachikawa, Takumu
    Ito, Naoya
    Ichikawa, Tomohiro
    Yoshimura, Masatoshi
    Takagi, Yukio
    Sawama, Yoshinari
    Ohya, Yutaka
    Sajiki, Hironao
    [J]. CATALYSTS, 2019, 9 (05):
  • [42] Calixarene-supported Pd-NHC complexes as efficient catalysts for scalable Suzuki-Miyaura cross-couplings
    Labattut, Axel
    Fayssal, Sandra Abi
    Buendia, Julien
    Abdellah, Ibrahim
    Huc, Vincent
    Martini, Cyril
    Schulz, Emmanuelle
    [J]. REACTION CHEMISTRY & ENGINEERING, 2020, 5 (08) : 1509 - 1514
  • [43] Efficient Sonogashira and Suzuki-Miyaura coupling reaction catalyzed by Pd-Nanoparticles
    Balsane, Kishor E.
    Shendage, Suresh S.
    Nagarkar, Jayashree M.
    [J]. JOURNAL OF CHEMICAL SCIENCES, 2015, 127 (03) : 425 - 431
  • [44] Enhanced heterogeneously catalyzed Suzuki-Miyaura reaction over SiliaCat Pd(0)
    Pandarus, Valerica
    Desplantier-Giscard, Delphine
    Gingras, Genevieve
    Ciriminna, Rosaria
    Cara, Piera Demma
    Beland, Francois
    Pagliaro, Mario
    [J]. TETRAHEDRON LETTERS, 2013, 54 (35) : 4712 - 4716
  • [45] Efficient Sonogashira and Suzuki-Miyaura coupling reaction catalyzed by Pd-Nanoparticles
    KISHOR E BALSANE
    SURESH S SHENDAGE
    JAYASHREE M NAGARKAR
    [J]. Journal of Chemical Sciences, 2015, 127 : 425 - 431
  • [46] Rh and Pd Nanoparticles Supported in a Polymeric Membrane: Evaluation in Hydrogenation and Suzuki-Miyaura Reactions
    Oliveira, Deyvid G. M.
    Rosa, Gilber R.
    Scheeren, Carla W.
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2017, 17 (12) : 9295 - 9301
  • [47] Immobilized palladium nanoparticles within polymers as active catalysts for Suzuki-Miyaura reaction
    Chen, Ting
    Mao, Fei
    Qi, Zhengliang
    Li, Yan
    Chen, Rizhi
    Wang, Yong
    Huang, Jun
    [J]. RSC ADVANCES, 2016, 6 (20): : 16899 - 16903
  • [48] Pd(AcO)2 supported by 1,3,5-triazine functionalized nanoporous polymers: Efficient and recyclable heterogeneous catalysts for Suzuki-Miyaura reaction
    Feng, Gaofeng
    He, Jingyao
    Deng, Wenshu
    Kong, Weiping
    [J]. KINETICS AND CATALYSIS, 2015, 56 (06) : 703 - 711
  • [49] The Suzuki-Miyaura reaction after the Nobel prize
    Beletskaya, Irina P.
    Alonso, Francisco
    Tyurin, Vladimir
    [J]. COORDINATION CHEMISTRY REVIEWS, 2019, 385 : 137 - 173
  • [50] Diethyl boronobenzylphosphonates as substrates in Suzuki-Miyaura reaction
    Rydzewska, Agata
    Mangold, Anna
    Wanat, Weronika
    Kafarski, Pawel
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2017, 192 (06) : 758 - 762
12345