Nickel-catalyzed kinetic resolution to achieve P-chiral phosphine oxides and sec-phosphine oxides

被引：5

作者：

Zhang, Xi ^{[1
,2
]}

Wang, Shao-Qiu ^{[1
]}

Yang, Shang-Dong ^{[1
,3
]}

机构：

[1] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[2] Hangzhou Med Coll, Sch Pharmaceut Sci, Hangzhou 310012, Peoples R China

[3] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2023年 / 66卷 / 09期

关键词：

P-chiral phosphine oxide; kinetic resolution; Ni catalysis; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; NUCLEOPHILIC-SUBSTITUTION; STEREOGENIC PHOSPHINES; PHOSPHORUS; ARYLATION; HYDROPHOSPHINATION; EFFICIENT; ALKENES; ACCESS;

D O I：

10.1007/s11426-023-1678-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

P-Chiral phosphines and sec-phosphine oxides (SPO) are found in a diverse range of compounds that play crucial roles in various fields, including asymmetric catalysis, materials, agrochemistry, and pharmaceutical chemistry. Herein, we describe an enantioselective Ni-catalyzed kinetic resolution of racemic sec-phosphine oxides to obtain the corresponding optically pure P-chiral phosphine oxides and sec-phosphine oxides, respectively. These products are versatile chiral phosphine building blocks that can be used to construct an extensive range of P-chiral phosphines.

引用

页码：2569 / 2575

页数：7

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