Lower Energy Excitation of Water Soluble Near-Infrared Emitting Mixed-Ligand Metallacrowns

被引：4
|
作者：
Nguyen, Tu N. [1 ,4 ]
Eliseeva, Svetlana V. [2 ]
Martinic, Ivana [2 ]
Carver, Peggy L. [3 ]
Lathion, Timothee [1 ]
Petoud, Stephane [2 ]
Pecoraro, Vincent L. [1 ]
机构：
[1] Univ Michigan, Dept Chem, Willard H Dow Labs, Ann Arbor, MI 48109 USA
[2] Ctr Biophys Mol, CNRS UPR 4301, Rue Charles Sadron, F-45071 Orleans 2, France
[3] Univ Michigan, Coll Pharm & Michigan Med, Ann Arbor, MI 48109 USA
[4] Helen Sci Res & Technol Dev Co Ltd, Ho Chi Minh City, Vietnam
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2023年 / 29卷 / 29期
基金：
美国国家科学基金会;
关键词：
lanthanide; luminescence; metallacrown; near-infrared; optical imaging; YTTERBIUM(III) COMPLEXES; HIGHLY LUMINESCENT; FLUOROPHORES; DESIGN;
D O I：
10.1002/chem.202300226
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
By combining advantages of two series of lanthanide(III)/zinc(II) metallacrowns (MCs) assembled using pyrazine- (pyzHA(2-)) and quinoxaline- (quinoHA(2-)) hydroximate building blocks ligands, we created here water-soluble mixed-ligand MCs with extended absorption to the visible range. The Yb-III analogue demonstrated improved photophysical properties in the near-infrared (NIR) range in cell culture media, facilitating its application for NIR optical imaging in living HeLa cells.
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收藏
页数：5
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