Fused ?5 -Phosphinines: Design, Syntheses, and Properties

被引：3

作者：

Hayashi, Minoru ^{[1
]}

Fujimoto, Shion ^{[1
]}

Ohta, Hidetoshi ^{[1
]}

机构：

[1] Ehime Univ, Grad Sch Sci & Engn, Dept Mat Sci & Biotechnol, Matsuyama 7908577, Japan

来源：

SYNLETT | 2023年 / 34卷 / 12期

基金：

日本学术振兴会;

关键词：

phosphinine; heteroaromatics; fluorescence; cyclization; coupling;

D O I：

10.1055/a-1979-6123

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of several heterocycle-fused ?5-phosphinines through intramolecular cyclization is described. The incorporation of a heteroatom affected their photophysical properties through perturbation of the LUMO level, which is in good contrast to the HOMO-based tuning by the C-4 substituent. The C-3-substituent-based property tuning provides a new guide to designing phosphinine-based fluorophores.

引用

页码：1492 / 1496

页数：5

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