Synthesis, characterization, and fluorescence properties of new polyethers derived from curcumin analogs

被引:0
|
作者
Ali, Walaa H. [1 ]
Bahili, Mohammed A. [1 ]
Saleh, Basil A. [1 ,3 ]
El-Hiti, Gamal A. [2 ,4 ]
机构
[1] Univ Basrah, Coll Sci, Dept Chem, Basrah, Iraq
[2] King Saud Univ, Coll Appl Med Sci, Dept Optometry, Riyadh, Saudi Arabia
[3] Univ Basrah, Coll Sci, Dept Chem, Basrah 61004, Iraq
[4] King Saud Univ, Coll Appl Med Sci, Dept Optometry, Riyadh 11433, Saudi Arabia
关键词
chalcones; curcumin analogs; fluorescence; polycondensation; polyethers; thermal stability; POLYMERS;
D O I
10.1177/17475198231221458
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polyether is a synthetic polymer that has low toxicity and, therefore, it is used in many applications. It can be used as a detergent, emulsifier, drug excipient, pesticide emulsifier, antiseptic, and papermaking additive agent. This study outlines the synthesis, characterization, and fluorescence evaluation of polyethers derived from curcumin analogs. Condensation polymerization of curcumin analogs and dibromoalkanes produces the corresponding polyethers. The Fourier-transform infrared and proton nuclear magnetic resonance spectroscopy confirmed the structures of the newly synthesized polyethers. The thermal stability and solubility of the synthesized polyethers of various solvents were investigated. They showed high stability at high temperatures as thermoplastics. The synthesized polyethers have fluorescent properties in solutions, and the absorption and intensity were dependent on the type of functional groups present in the polymers. The fluorination intensity of polyethers was found to be dependent on the presence of electron-donating groups, the pH of the solution, and the type of solvent used. One of the synthesized polyethers exhibited strong emissive properties at one or two specific wavelengths.
引用
收藏
页数:10
相关论文
共 50 条
  • [21] Synthesis, crystal structure, and anticancer properties of cyclic monocarbonyl analogs of curcumin
    Natesan Sundarmurthy Karthikeyan
    Kulathu Iyer Sathiyanarayanan
    Paduthapillai Gopal Aravindan
    P. Giridharan
    Medicinal Chemistry Research, 2011, 20 : 81 - 87
  • [22] PERFLUORINATED POLYETHERS SYNTHESIS AND PROPERTIES OF A NEW CLASS ON INERT FLUIDS
    SIANESI, D
    CHIMICA & L INDUSTRIA, 1968, 50 (02): : 206 - &
  • [23] SYNTHESIS, CHARACTERIZATION, AND ELECTRICAL-PROPERTIES OF POLYETHERS CONTAINING A QUINOLINE NUCLEUS
    PATEL, MS
    TRIVEDI, SG
    PATEL, HS
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1989, B28 (3-4): : 477 - 488
  • [24] SYNTHESIS OF NEW VALINOMYCIN ANALOGS AND THEIR PROPERTIES
    VINOGRAD.EI
    FONINA, LA
    SANASARY.AA
    RYABOVA, ID
    IVANOV, VT
    KHIMIYA PRIRODNYKH SOEDINENII, 1974, (02): : 233 - 240
  • [25] s-Triazine-Based Hyperbranched Polyethers: Synthesis, Characterization, and Properties
    Karak, Niranjan
    Roy, Buddhadeb
    Voit, Brigitte
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (18) : 3994 - 4004
  • [26] ETHYNYL-TERMINATED POLYETHERS FROM NEW END-CAPPING AGENTS - SYNTHESIS AND CHARACTERIZATION
    DELFORT, B
    LUCOTTE, G
    CORMIER, L
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (09) : 2451 - 2464
  • [27] Synthesis and characterization of new isoxazoles derived from benzosuberones
    Peesapati, Venkateswarlu
    Bathini, Srinivas
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2006, 45 (07): : 1753 - 1755
  • [28] Sugar derived crown ethers and their analogs: Synthesis and properties
    Jarosz, S
    Listkowski, A
    CURRENT ORGANIC CHEMISTRY, 2006, 10 (06) : 643 - 662
  • [29] Synthesis, Characterization, and Photoresponsive Behavior of New Azobenzene-Containing Polyethers
    Peris, Sergio
    Tylkowski, Bartosz
    Carles Ronda, Joan
    Garcia-Valls, Ricard
    Antonio Reina, Jose
    Giamberini, Marta
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (20) : 5426 - 5436
  • [30] Synthesis of crown analogs derived from bisnaphthol
    Kumar, S
    Mashraqui, SH
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1998, 37 (04): : 348 - 351