A THEORETICAL STUDY OF MACROMOLECULE INTERACTION WITH THE QUASI-FREE-STANDING AND EPITAXIAL GRAPHENE FORMED ON THE SILICON CARBIDE POLITYPES

被引：0

作者：

Lebedev, A. A. ^{[1
]}

Davydov, S. Yu. ^{[1
]}

机构：

[1] RAS, Ioffe Inst, St Petersburg, Russia

来源：

ST PETERSBURG POLYTECHNIC UNIVERSITY JOURNAL-PHYSICS AND MATHEMATICS | 2023年 / 16卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

two-level macromolecule model; single-layer graphene; semiconductor substrate;

D O I：

10.18721/JPM.16308

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A two-level model of an organic macromolecule has been put forward in order to analyze theoretically the interaction of dangling molecular orbitals of the organic macromolecule with quasi-free-standing and epitaxial graphene. The model initially contains a completely filled (HOMO) and empty (LOMO) levels. Within the framework of the standard adsorption approach, the interaction of these levels with quasi-free and epitaxial graphene was considered. Silicon carbide polytypes were considered as substrates. Our estimates showed that the maximum transition of electrons from dangling bonds to epitaxial graphene took place for the 3C-SiC substrate.

引用

页码：87 / 94

页数：8

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