Study on the Skeleton Mechanism of Second-Generation Biofuels Derived from Platform Molecules

被引:0
|
作者
Fan, Weiwei [1 ]
Du, Aichun [2 ]
Liu, Gang [1 ]
Liu, Qing [1 ]
Gao, Yuan [1 ]
机构
[1] Henan Inst Technol, Sch Vehicle & Traff Engn, Xinxiang 453003, Peoples R China
[2] Hami Polytech Univ, Dept Machinery & Elect Engn, Hami 839000, Peoples R China
关键词
skeleton mechanism; genetic algorithm; biomass fuel; LAMINAR BURNING VELOCITIES; IGNITION DELAY TIMES; 2,5-DIMETHYLFURAN; 2-METHYLFURAN; REACTIVITY; OXIDATION; CHEMISTRY; PRESSURE; FURAN;
D O I
10.3390/pr11061589
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper focuses on the combustion mechanism of furan-based fuels synthesized from lignocellulose. The fuel is a binary alternative fuel consisting of 2-methylfuran and 2,5-dimethylfuran derived from furfural. The key reactions affecting the combustion mechanism of this fuel were identified via path analysis, and the initial reaction kinetic mechanism was constructed using a decoupling methodology. Then, a genetic algorithm was used to optimize the initial mechanism. The final skeleton mechanism consisted of 67 species and 228 reactions. By comparing experimental data on ignition delay, component concentration, and laminar flame velocity under a wide range of conditions over various fundamental reactors, it was shown that the mechanism has the ability to predict the combustion process of this fuel well.
引用
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页数:17
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