Synthesis and Characterization of the Trichlates [N(CH3)4][Cl3CSO3], [NH4][Cl3CSO3], and the Dichlate [NH4][Cl2CHSO3]

被引：2

作者：

Mertens, Alisha ^{[1
]}

van Gerven, David ^{[1
]}

Lee, Hyunsong ^{[1
]}

Wickleder, Mathias S. ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, Greinstr 6, D-50939 Cologne, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2024年 / 27卷 / 04期

关键词：

Density functional calculations; dichloromethanesulfonate; IR spectroscopy; trichlate; trichloromethanesulfonate; X-ray diffraction; TRIFLUOROMETHANESULFONIC ACID; INFRARED-SPECTRA; ANIONS; SILVER; NQR;

D O I：

10.1002/ejic.202300535

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trichlates are the rarely-described bigger siblings of the well-known triflates. The cation has been obtained in form the [NH4]+ and the [N(CH3)(4)]+ salt, respectively. Moreover, the dichlate anion, [Cl2CHSO3]- could be characterized for the first time. image

引用

页数：7

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