Fast co-pyrolysis characteristics of high-alkali coal and polyethylene using infrared rapid heating

被引:15
|
作者
Li, Moshan [1 ]
Lu, Yiyu [1 ]
Hu, Erfeng [1 ]
Yang, Yang [2 ]
Tian, Yishui [3 ]
Dai, Chongyang [1 ]
Li, Chenhao [1 ]
机构
[1] Chongqing Univ, State Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
[2] Aston Univ, Bioenergy Res Grp, EBRI, Birmingham B4, England
[3] Minist Agr & Rural Affairs, Acad Agr Planning & Engn, Beijing 100125, Peoples R China
基金
中国国家自然科学基金;
关键词
Infrared heating; Fast co -pyrolysis; High alkali coal; Tar improvement; Polyethylene; PLASTIC WASTE; AROMATIC-HYDROCARBONS; CATALYTIC PYROLYSIS; FLUIDIZED-BED; BIOMASS; MECHANISM; TEMPERATURE; CONVERSION; BEHAVIOR; REMOVAL;
D O I
10.1016/j.energy.2023.126635
中图分类号
O414.1 [热力学];
学科分类号
摘要
Optimizing secondary reactions using infrared-fast pyrolysis has proved beneficial for investigating the copyrolysis behavior. In this study, co-pyrolysis of high-alkali coal (PC) and polyethylene at different temperatures, co-pyrolysis of polyethylene with demineralized coal (DP), and pyrolysis of raw high-alkali coal (RC) and demineralized coal (DC) were conducted in an infrared heating reactor. The results show that the co-pyrolysis promoted the formation of tar and the highest tar yield was 16.16% at 700 degrees C, and the PC tar yield was higher than that of RC, DC at 500 degrees C with 7.51% and 5.99% respectively. The tar yields of DP and PC were 7.49% and 11.80%, respectively, and the later had a slightly higher tar yield due to the interaction with AAEM. The addition of PE coupled infrared rapid heating can efficiently reduce the nitrogen and chlorine-containing fractions while increasing the content of long-chain alkanols and linear hydrocarbons. The content of organochlorines decreased from 2.95% at 500 degrees C to 1.00% at 800 degrees C. Alkanol and linear hydrocarbons have the highest content in the co-pyrolysis tar, with the total highest content of 61.56% at 600 degrees C.
引用
收藏
页数:9
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