Strengthening Pt/WOx interfacial interactions to increase the CO tolerance of Pt for hydrogen oxidation reaction

被引:5
|
作者
Long, Daojun [1 ,2 ]
Ping, Xinyu [1 ,2 ]
Ni, Jingtian [1 ,2 ]
Chen, Fadong [1 ,2 ]
Chen, Siguo [1 ,2 ]
Wei, Zidong [1 ,2 ]
Guo, Lin [3 ]
Zheng, Jinyu [3 ]
机构
[1] Chongqing Univ, Coll Chem & Chem Engn, Chongqing, Peoples R China
[2] State Key Lab Adv Chem Power Sources SKL ACPS, Chongqing, Peoples R China
[3] SINOPEC Res Inst Petr Proc Co, State Key Lab Catalyt Mat & React Engn, Beijing, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
METAL-SUPPORT INTERACTION; CARBON-MONOXIDE; FUEL-CELL; METHANOL;
D O I
10.1039/d3cc03990k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here, the modulation of the Pt electronic structure by the formation of an amorphous WOx overlayer on Pt nanoparticles is proposed. The resulting Pt/WOx@NC electrode shows exceptional CO oxidation potential (0.24 V vs. RHE) in aqueous test, and the corresponding membrane electrode assembly (MEA) steadily generates power in fuel cells fed with H-2 gas containing 1000 ppm CO.
引用
收藏
页码:13583 / 13586
页数:4
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