CF3-substituted sulfonium cations as efficient chalcogen bond donors towards cyanometalates

被引：7
|
作者：
Streit, Tim-Niclas [1 ]
Gomila, Rosa M. [2 ]
Sievers, Robin [1 ]
Frontera, Antonio [2 ]
Malischewski, Moritz [1 ]
机构：
[1] Free Univ Berlin, Inst Anorgan Chem, Fabeckstr 34-36, D-14195 Berlin, Germany
[2] Univ Illes Balears, Dept Chem, Crta Valldemossa Km 7-5, Palma De Mallorca 07122, Baleares, Spain
来源：
CRYSTENGCOMM | 2024年 / 26卷 / 05期
关键词：
TRIFLUOROMETHYLATING AGENTS;
D O I：
10.1039/d3ce01155k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
S-(CF3)Thianthrenium and S-(CF3)dibenzothiophenium cations form potent chalcogen bonds (ChBs) with [Mo(CO)(5)CN](-), yielding S2N2 supramolecular motifs. Crystal structures reveal shorter S & ctdot;N contacts opposite the CF3 group compared to the aryl substituents. The energetic features of the ChBs have been studied using DFT calculations demonstrating the structure guiding role of ChBs.
引用
收藏
页码：594 / 598
页数：5
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