A photocatalytic method for the regioselective carboxylation of azine C-H bonds using CO2

被引：16
|
作者：
Jiang, Yuan-Xu [1 ]
Yu, Da-Gang [1 ]
机构：
[1] Sichuan Univ, Chengdu, Peoples R China
来源：
NATURE SYNTHESIS | 2024年 / 3卷 / 03期
关键词：
D O I：
10.1038/s44160-023-00466-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The visible-light-driven thiolate-catalysed carboxylation of C(sp(2))-H bonds in azines using CO2 is demonstrated. This procedure can be applied to various azine substrates to obtain a range of N-heteroaromatic carboxylic acids with different functionalities, including bioactive molecules and carboxylated N-ligands.
引用
收藏
页码：305 / 306
页数：2
相关论文
共 50 条
  • [21] Photochemical Carboxylation of Activated C(sp3)-H Bonds with CO2
    Gui, Yong-Yuan
    Zhou, Wen-Jun
    Ye, Jian-Heng
    Yu, Da-Gang
    CHEMSUSCHEM, 2017, 10 (07) : 1337 - 1340
  • [22] Regioselective functionalization of unreactive C-H bonds
    Daugulis, Olafs
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [23] CO2 insertion into C-H bonds for carboxylic acid synthesis
    Xiao, Dianne
    Chant, Emma
    Yau, Allison
    Kanan, Matthew
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [24] Ni-Catalyzed Direct Carboxylation of an Unactivated C-H Bond with CO2
    Pei, Chunzhe
    Zong, Jiarui
    Han, Shanglin
    Li, Bin
    Wang, Baiquan
    ORGANIC LETTERS, 2020, 22 (17) : 6897 - 6902
  • [25] Rhodium(II)-Catalyzed Aryl C-H Carboxylation of 2-Pyridylphenols with CO2
    Cai, Zhihua
    Li, Shangda
    Gao, Yuzhen
    Li, Gang
    ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (20) : 4005 - 4011
  • [26] Rhodium(I)-Catalyzed Aryl C-H Carboxylation of 2-Arylanilines with CO2
    Gao, Yuzhen
    Cai, Zhihua
    Li, Shangda
    Li, Gang
    ORGANIC LETTERS, 2019, 21 (10) : 3663 - 3669
  • [27] Inserting CO2 into Aryl C-H Bonds of Metal-Organic Frameworks: CO2 Utilization for Direct Heterogeneous C-H Activation
    Gao, Wen-Yang
    Wu, Haifan
    Leng, Kunyue
    Sun, Yinyong
    Ma, Shengqian
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (18) : 5472 - 5476
  • [28] CO2 = CO + O: Redox-Neutral Lactamization and Lactonization of C-H Bonds with CO2
    Zhang, Zhen
    Ju, Tao
    Ye, Jian-Heng
    Yu, Da-Gang
    SYNLETT, 2017, 28 (07) : 741 - 750
  • [29] A GENERAL-METHOD OF PROMOTING OXIDATIVE ADDITION OF C-H BONDS TO IRIDIUM(I) USING AZINE PHOSPHINES
    PERERA, SD
    SHAW, BL
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (10) : 1203 - 1204
  • [30] Transition-Metal-Catalyzed Carboxylation of C-H Bonds
    Ackermann, Lutz
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (17) : 3842 - 3844
12345