Cp2Fe-Mediated Electrochemical Synthesis of Functionalized Compounds: Recent Advances

被引:2
|
作者
Zhu, Ranran R. [2 ]
Ma, Dumei M. [2 ]
Zhao, Yufen F. [1 ,3 ,4 ]
Wu, Ju [1 ]
机构
[1] Ningbo Univ, Inst Drug Discovery Technol, Zhejiang 315211, Peoples R China
[2] Ningbo Univ, Inst Mass Spectrometry, Ningbo 315211, Zhejiang, Peoples R China
[3] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Fujian, Peoples R China
[4] Xiamen Univ, Coll Chem & Chem Engn, Key Lab Chem Biol Fujian Prov, Xiamen 361005, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
Cp2Fe; Cp2Fe-mediated; electrolysis; indirect oxidation; heterocycles; C-H FUNCTIONALIZATION; ORGANIC ELECTROSYNTHESIS; FERROCENE; GENERATION; RADICALS;
D O I
10.1002/ejoc.202400021
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Unlike traditional organic methods, electrosynthesis has emerged as an environmentally friendly and sustainable approach to generate a series of functionalized compounds. In this process, the traceless electron serves as the redox agent, eliminating the need for stoichiometric oxidants or reductants. In contrast to direct electrolysis, redox-mediated electrolysis has the ability to overcome kinetic inhibitions and achieve diverse selectivity under mild conditions. This has garnered increasing attention from the synthetic community, especially in the past few years. This review will focus on Cp2Fe-mediated electrosynthesis of diversified functionalized compounds through C-N, C-C, C-P and C-O bond formation over the past decade.
引用
收藏
页数:14
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