Effect of Oxides of Various Metals on the Physicochemical Properties of Glass in the PbO-CdO-SiO2-B2O3-Al2O3 System

被引:1
|
作者
Lozinskii, N. S. [1 ]
Moroz, Ya. A. [1 ]
Lopanov, A. N. [2 ]
机构
[1] Litvinenko Inst Phys Organ Chem & Coal Chem, Doneck 283114, Russia
[2] Shukhov Belgorod State Technol Univ, Belgorod 308012, Russia
关键词
lead borosilicate glasses; metal oxides; phase composition; acid-base; redox and electrical properties; SUBSOLIDUS PHASE-EQUILIBRIA; ELECTRICAL-PROPERTIES; SILICATE-GLASSES; BURIED RESISTORS; BORATE GLASSES; LEAD; CONDUCTIVITY; PART;
D O I
10.1134/S1087659622601101
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The physicochemical processes occurring in glasses of the PbO-CdO-SiO2-B2O3-Al2O3 system after high-temperature contact with oxides of various metals-CuO, NiO, Al2O3, TiO2, Nb2O5, and WO3, as well as the electrical resistance of the obtained glasses-are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O2- ion in each specific composition.
引用
收藏
页码:136 / 149
页数:14
相关论文
共 50 条
  • [41] Characteristics of a SiO2-B2O3-Al2O3-BaCO3-PbO2-ZnO glass-ceramic sealant for SOFCs
    Wang, Ruifang
    Lu, Zhe
    Liu, Chaoqian
    Zhu, Ruibin
    Huang, Xiqiang
    Wei, Bo
    Ai, Na
    Su, Wenhui
    JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 432 (1-2) : 189 - 193
  • [42] The electret properties of SiO2/Al2O3/PbO welded glass film
    Huang, ZQ
    Zhao, MZ
    Xu, Z
    Sha, LZ
    ISE 9 - 9TH INTERNATIONAL SYMPOSIUM ON ELECTRETS, PROCEEDINGS, 1996, : 157 - 161
  • [43] Effect of Cr2O3 on Solubility and Thermo-Physical Properties of BaO-CaO-Al2O3-B2O3-SiO2 Glass System
    Goswami, M.
    Kumar, Rakesh
    Patil, A. S.
    Sahu, A. K.
    Kothiyal, G. P.
    SOLID STATE PHYSICS, PTS 1 AND 2, 2012, 1447 : 609 - 610
  • [44] Effect of Gamma-Ray Irradiation on the Optical Properties of PbO-B2O3-SiO2 and Bi2O3-B2O3-SiO2 Glasses
    Ou, Yuwen
    Baccaro, Stefania
    Zhang, Yaping
    Yang, Yunxia
    Chen, Guorong
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (02) : 338 - 341
  • [45] Effect of annealing on properties of R2O-SiO2-B2O3 glass
    Shi, Yu
    Jia, Jinsheng
    Sun, Yong
    Wang, Caili
    Lian, Jiao
    Xu, Huichao
    AOPC 2020: OPTICS ULTRA PRECISION MANUFACTURING AND TESTING, 2020, 11568
  • [46] Effect of Al2O3 on phase separation and microstructure of R2O-B2O3-Al2O3-SiO2 glass system (R = Li, Na)
    Kwinda, Tovhowani Innocent
    Koppka, Sharon
    Sander, Stephan A. H.
    Kohns, Richard
    Enke, Dirk
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2020, 531
  • [47] CRYSTALLIZATION OF A PBO-BAO-TIO2-AL2O3-SIO2 GLASS
    SHYU, JJ
    YANG, YS
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (06) : 1463 - 1468
  • [48] DAS SYSTEM B2O3-AL2O3-SIO2
    SCHOLZE, H
    ANGEWANDTE CHEMIE, 1954, 66 (19): : 619 - 619
  • [49] Study of glass structures and crystalline phases in the PbO-Al2O3-SiO2 system
    Mylyanych, AO
    Sheredko, MA
    Melnyk, SK
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1999, 14 (03) : 513 - 521
  • [50] MOSSBAUER STUDY IN GLASS SYSTEM PBO.2B2O3.FE2O3
    SEKHON, SS
    KAMAL, R
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1978, 28 (02) : 189 - 192