Nitrogen ligand influence on the CO-assisted ruthenium-catalyzed reductive amination

被引：0
|
作者：
Kozlov, Andrey S. [1 ]
Afanasyev, Oleg I. [1 ]
Losev, Mikhail A. [1 ,2 ]
Godovikova, Maria I. [1 ]
Chusov, Denis [1 ,3 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[2] Natl Res Univ Higher Sch Econ HSE Univ, Moscow 101000, Russia
[3] GV Plekhanov Russian Univ Econ, Moscow 117997, Russia
来源：
MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 02期
基金：
俄罗斯科学基金会;
关键词：
ruthenium; nitrogen-containing ligands; reductive amination; amines; aldehydes; carbon monoxide; catalysis; CARBON-MONOXIDE; MOLECULAR-HYDROGEN; NITROARENES; ALDEHYDES; KETONES; AMINES;
D O I：
10.1016/j.mencom.2023.02.008
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A representative set of amines and N-heterocycles was applied as additives in the CO-assisted Ru-catalyzed reductive amination of p-anisaldehyde with p-anisidine. Among the tested ligands, pyridine caused a strong activation for low active aliphatic substrates while bidentate heterocyclic ligands possess significant inhibition of catalyst for the majority of substrates.
引用
收藏
页码：174 / 176
页数：3
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