[6-(Thiophen-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate

被引：3
|
作者：
Kouvatsis, Panagiotis [1 ]
Glykos, Dimitrios [1 ]
Plakatouras, John C. [1 ,2 ]
Malandrinos, Gerasimos [1 ]
机构：
[1] Univ Ioannina, Dept Chem, Lab Inorgan Chem, Ioannina 45110, Greece
[2] Univ Res Ctr Ioannina, Inst Mat Sci & Comp, Ioannina 45110, Greece
来源：
MOLBANK | 2023年 / 2023卷 / 01期
关键词：
heteroleptic copper(I) complexes; photoluminescence; diimine ligands; X-ray diffraction; CU-I COMPLEXES; CU(I) COMPLEXES; MONONUCLEAR; EMISSION;
D O I：
10.3390/M1605
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The novel heteroleptic copper (I) complex [6-(thiophen-2-yl)-2,2 '-bipyridine]bis(triphenylphosphine) copper(I) tetrafluoroborate (1), formulated as [CuL(PPh3)(2)]BF4, was synthesized in two steps, utilizing the diimine type ligand L = 6-(thiophen-2-yl)-2,2 '-bipyridine and triphenylphosphine (PPh3). The compound was characterized both in the solid state and in solution by employing single crystal X-ray diffraction, IR, UV, and NMR spectroscopies. The complex is an orange emitter that demonstrates a photoluminescence quantum yield of 2.6% in the solid state.
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页数：8
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