Visible Light-Mediated Selective Aerobic Oxidation of Alcohols Catalyzed by Disulfide in Batch and Flow

被引：1

作者：

Lu, Yue ^{[1
]}

Zhao, Jingnan ^{[1
]}

Sun, Huinan ^{[1
]}

Li, Jianing ^{[1
]}

Yu, Zongyi ^{[1
]}

Ma, Cunfei ^{[1
]}

Zhu, Hongfei ^{[1
]}

Meng, Qingwei ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, Sch Chem Engn, Dept Pharmaceut Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[2] Dalian Univ Technol, Ningbo Inst, Ningbo 315000, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 06期

基金：

中国国家自然科学基金;

关键词：

THIYL-RADICAL CATALYST; TRANSITION-METAL-FREE; PHOTOCATALYTIC OXIDATION; ALKENES; SYSTEM;

D O I：

10.1021/acs.joc.3c02718

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selective aerobic oxidation of alcohols in batch and flow can be realized under light irradiation, utilizing disulfide as the photocatalyst, and a variety of primary and secondary alcohols were converted to the corresponding aldehydes or ketones in up to 99% yield and high selectivity. The reaction efficiency could be increased even further by combining a continuous-flow strategy. Detailed mechanistic studies have also been achieved to determine the role of oxygen and disulfides in this oxidation.

引用

页码：3868 / 3874

页数：7

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