Visible Light-Mediated Selective Aerobic Oxidation of Alcohols Catalyzed by Disulfide in Batch and Flow

被引：1
|
作者：
Lu, Yue [1 ]
Zhao, Jingnan [1 ]
Sun, Huinan [1 ]
Li, Jianing [1 ]
Yu, Zongyi [1 ]
Ma, Cunfei [1 ]
Zhu, Hongfei [1 ]
Meng, Qingwei [1 ,2 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, Dept Pharmaceut Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Ningbo Inst, Ningbo 315000, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 06期
基金：
中国国家自然科学基金;
关键词：
THIYL-RADICAL CATALYST; TRANSITION-METAL-FREE; PHOTOCATALYTIC OXIDATION; ALKENES; SYSTEM;
D O I：
10.1021/acs.joc.3c02718
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selective aerobic oxidation of alcohols in batch and flow can be realized under light irradiation, utilizing disulfide as the photocatalyst, and a variety of primary and secondary alcohols were converted to the corresponding aldehydes or ketones in up to 99% yield and high selectivity. The reaction efficiency could be increased even further by combining a continuous-flow strategy. Detailed mechanistic studies have also been achieved to determine the role of oxygen and disulfides in this oxidation.
引用
收藏
页码：3868 / 3874
页数：7
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