Recent advances in Pd-catalyzed asymmetric cyclization reactions

被引:19
|
作者
Xu, Bing [1 ,2 ]
Wang, Quanpu [1 ]
Fang, Chao [1 ]
Zhang, Zhan-Ming [1 ,3 ]
Zhang, Junliang [1 ,3 ,4 ]
机构
[1] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China
[2] Zhuhai Fudan Innovat Inst, Zhuhai 519000, Peoples R China
[3] Fudan Zhangjiang Inst, Shanghai 201203, Peoples R China
[4] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
基金
中国博士后科学基金; 国家重点研发计划; 中国国家自然科学基金;
关键词
ENANTIOSELECTIVE TOTAL-SYNTHESIS; OXIDATIVE CARBOCYCLIZATION-BORYLATION; ALPHA-ARYLATIVE DESYMMETRIZATION; ALKENE CARBOAMINATION REACTIONS; CROSS-COUPLING REACTIONS; REDUCTIVE HECK REACTION; CHIRAL GAMMA-LACTAMS; C-H ACTIVATION; 3+2 CYCLOADDITION; CASCADE REACTION;
D O I
10.1039/d3cs00489a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Over the past few decades, there have been major developments in transition metal-catalyzed asymmetric cyclization reactions, enabling the convenient access to a wide spectrum of structurally diverse chiral carbo- and hetero-cycles, common skeletons found in fine chemicals, natural products, pharmaceuticals, agrochemicals, and materials. In particular, a plethora of enantioselective cyclization reactions have been promoted by chiral palladium catalysts owing to their outstanding features. This review aims to collect the latest advancements in enantioselective palladium-catalyzed cyclization reactions over the past eleven years, and it is organized into thirteen sections depending on the different types of transformations involved. This review aims to collect advancements in enantioselective palladium-catalyzed cyclization reactions over the past eleven years, and it is organized into thirteen sections depending on the different types of transformations involved.
引用
收藏
页码:883 / 971
页数:89
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