Synthesis, structure and properties of RNiBN (R = rare-earth elements)

被引：0

作者：

Song, Shi-jie ^{[1
]}

Li, Bai-Zhuo ^{[1
]}

Zhu, Qin-Qing ^{[2
]}

Ren, Zhi ^{[2
]}

Cao, Guang-Han ^{[1
]}

机构：

[1] Zhejiang Univ, Interdisciplinary Ctr Quantum Informat, Sch Phys, Hangzhou 310058, Peoples R China

[2] Westlake Univ, Sch Sci, 18 Shilongshan Rd, Hangzhou 310064, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2024年 / 970卷

基金：

中国国家自然科学基金;

关键词：

Nickel nitridoborates; Rare-earth magnetism; Giant magnetocaloric effect; SUPERCONDUCTING LUNI2B2C; CRYSTAL-STRUCTURE; MAGNETISM; ORDER; INTERPLAY; SERIES; TB; HO; DY; ER;

D O I：

10.1016/j.jallcom.2023.172491

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the structural and physical properties of new nitridoborates RNiBN (R = Nd, Sm, Gd, Tb, Dy, Ho, and Er). These compounds crystallize in a tetragonal LaNiBN-type structure with two-dimensional Ni2B2 and RN layers. The physical properties measurements indicate that they are antiferromagnetic metals. For R = Gd and Ho, a successive magnetic transition was observed below N e ' el temperature, possibly associated with spin reorientation due to Ruderman-Kittel-Kasuya-Yosida interaction. A giant magnetocaloric effect was measured in the R = Er and Ho compounds, which is related to a field-induced first-order metamagnetic transition from antiferromagnetic to ferromagnetic state. Our results indicate that RNiBN (R = Er and Ho) may be promising candidates for low temperature magnetic refrigeration

引用

页数：8

共 50 条

[21] CATALYTIC PROPERTIES OF MONOPHOSPHATES OF RARE-EARTH ELEMENTS
MELNIKOV, PP
KOLDASHEVA, EM
KUBASOV, AA
PICHARDO, KL
INORGANIC MATERIALS, 1986, 22 (06) : 919 - 920
[22] Synthesis, structure and optical properties of rare-earth benzene carboxylates
Mahata, Partha
Ramya, K. V.
Natarajan, Srinivasan
DALTON TRANSACTIONS, 2007, (36) : 4017 - 4026
[23] Synthesis, Structure and Luminescence Properties of Rare-Earth Double Phosphates
Terebilenko, Katerina V.
Slobodyanik, Nikolay S.
Zatovsky, Igor V.
Baumer, Vyacheslav N.
OXIDE MATERIALS FOR ELECTRONIC ENGINEERING - FABRICATION, PROPERTIES AND APPLICATIONS, 2013, 200 : 33 - +
[24] Synthesis, Structure, and Magnetic Properties of Rare-Earth Benzoborole Complexes
Zhu, Dezhao
Wang, Mengmeng
Guo, Lulu
Shi, Wei
Li, Jianfeng
Cui, Chunming
ORGANOMETALLICS, 2021, 40 (15) : 2394 - 2399
[25] Synthesis, structure, and catalytic properties of rare-earth ternary sulfates
Perles, J
Fortes-Revilla, C
Gutiérrez-Puebla, E
Iglesias, M
Monge, MA
Ruiz-Valero, C
Snejko, N
CHEMISTRY OF MATERIALS, 2005, 17 (10) : 2701 - 2706
[26] LINES OF THE RARE-EARTH ELEMENTS IN THE SPECTRUM OF R ANDROMEDAE
BIDELMAN, WP
ASTROPHYSICAL JOURNAL, 1953, 117 (03): : 377 - 379
[27] RARE-EARTH ELEMENTS
DUSING, G
CHEMIKER-ZEITUNG, 1965, 89 (22): : 788 - &
[28] RARE-EARTH ELEMENTS
REINHARDT, K
CHEMIE IN UNSERER ZEIT, 1984, 18 (01) : 24 - 34
[29] Magnetic properties of oxides with high concentrations of rare-earth elements R6AO12 (R = rare-earth element, A = Mo or W)
Hase, Masashi
Tsujii, Naohito
Suzuki, Hiroyuki S.
Sakai, Osamu
Mamiya, Hiroaki
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2021, 523
[30] Enantiopure Benzamidinate/Cyclooctatetraene Complexes of the Rare-Earth Elements: Synthesis, Structure, and Magnetism
He, Meng
Chen, Xiao
Bodenstein, Tilmann
Nyvang, Andreas
Schmidt, Sebastian F. M.
Peng, Yan
Moreno-Pineda, Eufemio
Ruben, Mario
Fink, Karin
Gamer, Michael T.
Powell, Annie K.
Roesky, Peter W.
ORGANOMETALLICS, 2018, 37 (21) : 3708 - 3717

← 1 2 3 4 5 →