Detonation development in PRF/air mixtures under engine-relevant conditions

The development of advanced boosted internal combustion engines (ICEs) is constrained by super-knock which is closely associated with end gas autoignition and detonation development. The present study numer-ically investigates the transient autoignition and detonation development processes under engine-relevant conditions for primary reference fuel (PRF) consisting of n-heptane and isooctane. The effects of PRF com-position are systematically examined. By considering the transient local sound speed rather than its initial value, a new non-dimensional parameter is proposed to assess the transient chemical-acoustic interaction and to quantify the autoignition modes. Two detonation sub-modes, normal and over-driven detonation, are identified and the corresponding mechanisms are interpreted. For the over-driven detonation, there exist two developing regimes with weak/strong chemical-acoustic coupling and slow/rapid pressure enhancement. It is found that the maximum pressure caused by autoignition decreases with the blending ratio of isooctane, mainly due to the increase in excitation time. Besides, the strongest detonation induced by hot spot usually occurs within the over-driven detonation sub-regime. Its condition can be well quantified by the new non -dimensional parameter proposed in work and its strength is determined by the ratio of hot spot acoustic time to excitation time. The deviation of transient autoignition front propagation from prediction based on homogenous ignition is mainly attributed to the non-uniform compression effect caused by gradually en-hanced pressure wave, while the influence of heat conduction and mass diffusion is negligible. The initial expansion stage dominating the induction period of local autoignition is greatly influenced by the compres-sion of pressure wave. Therefore, the continuously enhanced pressure wave non-uniformly changes the local ignition delay (i.e. reduces its spatial gradient) within the hot spot and thereby accelerates the autoignition front propagation. The relationship among the parameters quantifying the detonation propensity is assessed and interpreted. The present study provides helpful understanding of detonation development under engine conditions.& COPY; 2022 The Combustion Institute. Published by Elsevier Inc. All rights reserved.