Ag@Fe3O4 nanoparticles decorated NrGO nanocomposite for supercapacitor application

被引:15
|
作者
Ciplak, Zafer [1 ]
Yildiz, Nuray [2 ]
机构
[1] Sivas Cumhuriyet Univ, Fac Engn, Dept Chem Engn, TR-58140 Sivas, Turkiye
[2] Ankara Univ, Fac Engn, Dept Chem Engn, TR-06100 Ankara, Turkiye
关键词
Graphene; Core-shell nanoparticles; Supercapacitors; Nanocomposite; PERFORMANCE ELECTRODE MATERIALS; STEP HYDROTHERMAL SYNTHESIS; GRAPHENE OXIDE COMPOSITE; REDUCED GRAPHENE; AG NANOPARTICLES; DOPED GRAPHENE; CHEMICAL-REDUCTION; GREEN SYNTHESIS; NITROGEN; FABRICATION;
D O I
10.1016/j.jallcom.2023.169024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
There is still a great need for production and design of electrode materials with superior electrochemical properties for supercapacitor application. Nanocomposites containing graphene-based metal-metal oxide nanostructures are promising electrode materials because of their high conductivity, excellent surface properties, and effective charge storage with both EDLC and pseudocapacitance mechanisms. In this study, Ag@Fe3O4 core@shell nanoparticles decorated nitrogen doped reduced graphene oxide (NrGO) was ob-tained with a facile and simple method. On the surface of NrGO nanosheets, Ag nanoparticles were found to be coated with Fe3O4 nanoparticles with a particle size of 5-12 nm. The electrochemical measurements of NrGO-Ag@Fe3O4 nanocomposite were carried out in a two-electrode cell. The ternary nanocomposite ex-hibited 212.2 F/g specific capacitance at a current density of 1 A/g, as well as high cyclic stability, the NrGO-Ag@Fe3O4 nanocomposite retained 77 % of its specific capacitance after 10,000 cycles. The Ag@Fe3O4 de-corated NrGO nanocomposite indicates great potential as an electrode material for supercapacitor appli-cations.(c) 2023 Elsevier B.V. All rights reserved.
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页数:13
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