Microwave-assisted, ionic liquid-catalyzed aminolysis and alcoholysis of phosphinic derivatives: the interconversion of phosphinates and phosphinic amides

被引：4

作者：

Keglevich, Gyorgy ^{[1
]}

Harsagi, Nikoletta ^{[1
]}

Szilagyi, Sarolta ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Fac Chem Technol & Biotechnol, Dept Organ Chem & Technol, H-1521 Budapest, Hungary

来源：

GREEN CHEMISTRY | 2023年 / 25卷 / 24期

关键词：

METHYL PHENYL; ESTERIFICATION; MECHANISM; KINETICS; ACIDS; DIMETHYL; AMINES;

D O I：

10.1039/d3gc02711b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chlorine-free and simple method was developed for the preparation of alkylamino-3-phospholene oxides and for the diastereoselective synthesis of alkylaminophospholane oxides by the MW-assisted ionic liquid-catalyzed aminolysis of the corresponding cyclic phosphinates. The opposite reaction, the alcoholysis of cyclic phosphinic amides, was also elaborated. The interconversion of phosphinates and phosphinic amides may be of more general value.

引用

页码：10372 / 10380

页数：9

共 25 条

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