Microwave-assisted, ionic liquid-catalyzed aminolysis and alcoholysis of phosphinic derivatives: the interconversion of phosphinates and phosphinic amides

被引：4

作者：

Keglevich, Gyorgy ^{[1
]}

Harsagi, Nikoletta ^{[1
]}

Szilagyi, Sarolta ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Fac Chem Technol & Biotechnol, Dept Organ Chem & Technol, H-1521 Budapest, Hungary

来源：

GREEN CHEMISTRY | 2023年 / 25卷 / 24期

关键词：

METHYL PHENYL; ESTERIFICATION; MECHANISM; KINETICS; ACIDS; DIMETHYL; AMINES;

D O I：

10.1039/d3gc02711b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chlorine-free and simple method was developed for the preparation of alkylamino-3-phospholene oxides and for the diastereoselective synthesis of alkylaminophospholane oxides by the MW-assisted ionic liquid-catalyzed aminolysis of the corresponding cyclic phosphinates. The opposite reaction, the alcoholysis of cyclic phosphinic amides, was also elaborated. The interconversion of phosphinates and phosphinic amides may be of more general value.

引用

页码：10372 / 10380

页数：9

共 25 条

[1] Novel Synthesis of Phosphinates by the Microwave-Assisted Esterification of Phosphinic Acids
Kiss, Nora Zsuzsa
Ludanyi, Krisztina
Drahos, Laszlo
Keglevich, Gyorgy
SYNTHETIC COMMUNICATIONS, 2009, 39 (13) : 2392 - 2404
[2] Ionic liquid-catalyzed and microwave-assisted syntheses of pyrrolizine- and indolizinedione derivatives
Sakhautdinov, I. M.
Batyrshin, I. R.
Sergeeva, N. A.
Galin, F. Z.
Yunusov, M. S.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 48 (06) : 788 - 792
[3] Ionic liquid-catalyzed and microwave-assisted syntheses of pyrrolizine- and indolizinedione derivatives
I. M. Sakhautdinov
I. R. Batyrshin
N. A. Sergeeva
F. Z. Galin
M. S. Yunusov
Russian Journal of Organic Chemistry, 2012, 48 : 788 - 792
[4] Synthesis of Cyclic Phosphinates by Microwave-Assisted Ionic-Liquid-Promoted Alcoholysis
Harsági, Nikoletta
Kiss, Nóra Zsuzsa
Drahos, László
Keglevich, György
Synthesis (Germany), 2021, 54 (17) : 3899 - 3905
[5] Synthesis of Cyclic Phosphinates by Microwave-Assisted Ionic-Liquid-Promoted Alcoholysis
Harsagi, Nikoletta
Kiss, Nora Zsuzsa
Drahos, Laszlo
Keglevich, Gyorgy
SYNTHESIS-STUTTGART, 2022, 54 (17): : 3899 - 3905
[6] Microwave-assisted direct esterification of cyclic phosphinic acids in the presence of ionic liquids
Kiss, Nora Zsuzsa
Keglevich, Gyoergy
TETRAHEDRON LETTERS, 2016, 57 (09) : 971 - 974
[7] Microwave-Assisted Ionic Liquid-Catalyzed Selective Monoesterification of Alkylphosphonic Acids-An Experimental and a Theoretical Study
Harsagi, Nikoletta
Henyecz, Reka
Abranyi-Balogh, Peter
Drahos, Laszlo
Keglevich, Gyorgy
MOLECULES, 2021, 26 (17):
[8] A chlorine-free microwave-assisted, ionic liquid-catalyzed esterification of arylsulfonic acids with alcohols: an experimental and theoretical study
Huszar, Bianka
Mucsi, Zoltan
Keglevich, Gyorgy
ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (47) : 9249 - 9258
[9] Ionic liquid-catalyzed, microwave-assisted green synthesis of novel Coumarin-Schiff bases: Characterization, molecular docking, biological and DFT studies
Kurahatti, Sunita
Anchi, Athmanand
Rathod, Manohar R.
Pawashe, Geeta M.
Kalkhambkar, Rajesh G.
Kurkuri, Mahaveer D.
JOURNAL OF MOLECULAR STRUCTURE, 2025, 1324
[10] Microwave-assisted synthesis of 1,2-benzisoxazole derivatives in ionic liquid
Shelke, Kiran F.
Sapkal, Suryakant B.
Shitole, Nana V.
Shingate, Bapurao B.
Shingare, Murlidhar S.
ORGANIC COMMUNICATIONS, 2009, 2 (03) : 72 - 78

← 1 2 3 →