Waste newspaper driven activated carbon to remove polycyclic aromatic hydrocarbon from wastewater

被引:12
|
作者
Nahar, Aynun [1 ]
Akbor, Md. Ahedul [1 ,5 ]
Pinky, Nigar Sultana [2 ]
Chowdhury, Nushrat Jahan [1 ]
Ahmed, Shamim [1 ]
Gafur, Md. Abdul [3 ]
Akhtar, Umme Sarmeen [2 ]
Quddus, Md. Saiful [2 ]
Chowdhury, Fariha [4 ]
机构
[1] Bangladesh Council Sci & Ind Res BCSIR, Inst Natl Analyt Res & Serv INARS, Dhaka, Bangladesh
[2] Bangladesh Council Sci & Ind Res BCSIR, Inst Glass & Ceram Res & Testing IGCRT, Dhaka, Bangladesh
[3] Bangladesh Council Sci & Ind Res BCSIR, Pilot Plant & Proc Dev Ctr PP & PDC, Dhaka, Bangladesh
[4] Bangladesh Council Sci & Ind Res BCSIR, Biomed & Toxicol Res Inst BTRI, Dhaka 1205, Bangladesh
[5] Inst Natl Analyt Res & Serv INARS, Bangladesh Council Sci & Ind Res BCSIR, Dhaka 1205, Bangladesh
关键词
Benzo[ghi]perylene (BghiP); Indeno[1,2,3-cd]pyrene (IP); Removal efficiency; Adsorption capacity; Adsorption isotherm; Adsorption kinetics; ADSORPTION; BIOCHAR; OXIDATION; ISOTHERM; ADSORBENTS; DESORPTION; SORPTION; AEROGEL; PHENOL; PAHS;
D O I
10.1016/j.heliyon.2023.e17793
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In this study, a carbon-based adsorbent was developed from waste newspaper through pyrolysis at 800 degrees C to evaluate the removal efficiency of polycyclic aromatic hydrocarbons (Benzo[ghi] perylene (BghiP) and Indeno [1,2,3-cd] pyrene (IP)) from wastewater. The surface area of the developed adsorbent was estimated at 509.247m2g-1 which allowed the adsorption of the PAHs from wastewater. The maximum adsorption capacity was estimated at 138.436 & mu;g g- 1 and 228.705 & mu;g g � 1 for BghiP and IP, respectively and the highest removal efficiency was observed at pH 2. Around 91% removal efficiency was observed at pH 7 for both pollutants. Experimental adsorption data were fit for pseudo-second-order kinetics and Langmuir isotherm models, which demonstrate electrostatic interaction, monolayered deposition, hydrogen bonding, and & pi;-& pi; interaction between adsorbate and adsorbent which play a significant role in adsorption. The regeneration study described that the developed adsorbent could be able to intake 52.75% BghiP and 48.073% IP until the 8th and 6th cycles, respectively. The removal efficiency of the adsorbent in the real sample was also evaluated. This study will provide a method to convert waste material into adsorbent and will remove PAHs from wastewater as a function of pollutant mitigation and waste management.
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页数:13
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