Synthesis of an Alternating Polycation with the Dense 1,2,3-Triazole Backbone

被引：2
|
作者：
Omae, Tomoki [1 ]
Nakahata, Masaki [1 ]
Kamon, Yuri [2 ]
Hashidzume, Akihito [1 ]
机构：
[1] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Machikaneyama Cho, Toyonaka, Osaka 5600043, Japan
[2] Osaka Univ, Grad Sch Sci, Adm Dept, Machikaneyama Cho, Toyonaka, Osaka 5600043, Japan
来源：
SYNLETT | 2024年 / 35卷 / 11期
关键词：
alternating copolymers; polycations; dense triazole backbone; copper(I)-catalyzed azide-alkyne cycloaddition; heterodimers; OLIGOMERS;
D O I：
10.1055/a-2214-5397
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Polycations are an important class of water-soluble polymers because they form polyion complexes with DNA. Thus, the synthesis of polycations with controlled monomer sequences will be of increasing importance for the formation of well-defined polyion complexes. In this study, cationic homopolymer and alternating copolymer with the dense triazole backbone were synthesized by copper(I)catalyzed azide-alkyne cycloaddition polymerization. The polycations obtained were characterized by potentiometric and turbidimetric titrations, and by complex formation with poly(acrylic acid).
引用
收藏
页码：1301 / 1305
页数：5
相关论文
共 50 条
  • [1] Synthesis of a New Polyanion Possessing Dense 1,2,3-Triazole Backbone
    Xu, Linlin
    Kamon, Yuri
    Hashidzume, Akihito
    POLYMERS, 2021, 13 (10)
  • [2] Synthesis of Stereoregular Uniform Oligomers Possessing a Dense 1,2,3-Triazole Backbone
    Kamon, Yuri
    Miura, Junji
    Okuno, Koji
    Yamasaki, Shota
    Nakahata, Masaki
    Hashidzume, Akihito
    MACROMOLECULES, 2023, 56 (01) : 292 - 304
  • [3] Synthesis of an alternating copolymer of the dense 1,2,3-triazole backbone carrying t-butyl ester and nitrile side chains
    Xu, Linlin
    Nakahata, Masaki
    Kamon, Yuri
    Hashidzume, Akihito
    JOURNAL OF POLYMER SCIENCE, 2024, 62 (06) : 937 - 945
  • [4] Synthesis of New Thermoresponsive Polymers Possessing the Dense1,2,3-Triazole Backbone
    Okuno, Koji
    Arisawa, Takuya
    Kamon, Yuri
    Hashidzume, Akihito
    Winnik, Francoise M.
    LANGMUIR, 2022, 38 (17) : 5156 - 5165
  • [5] Synthesis and Characterization of Azido-Functionalized 1,2,3-Triazole and Fused 1,2,3-Triazole
    Cao, Yupeng
    Huang, Haifeng
    Wang, Limin
    Lin, Xiangyang
    Yang, Jun
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (07): : 4301 - 4308
  • [6] Synthesis and Characterization of Azido-Functionalized 1,2,3-Triazole and Fused 1,2,3-Triazole
    Cao, Yupeng
    Huang, Haifeng
    Wang, Limin
    Lin, Xiangyang
    Yang, Jun
    JOURNAL OF ORGANIC CHEMISTRY, 2023,
  • [7] SYNTHESIS OF 1,2,3-TRIAZOLE DERIVATIVES
    CARBONI, S
    DASETTIMO, A
    FERRARINI, PL
    LIVI, O
    TONETTI, I
    CHIMICA & L INDUSTRIA, 1976, 58 (12): : 878 - 878
  • [8] Synthesis of 1,2,3-Triazole Derivatives
    Jiang Yubo
    Kuang Chunxiang
    PROGRESS IN CHEMISTRY, 2012, 24 (10) : 1983 - 1994
  • [9] Synthesis of Stereoregular Uniform Oligomers Possessing a Dense 1,2,3-Triazole Backbone (vol 56, pg 292, 2023)
    Kamon, Yuri
    Miura, Junji
    Okuno, Koji
    Yamasaki, Shota
    Nakahata, Masaki
    Hashidzume, Akihito
    MACROMOLECULES, 2023, 56 (15) : 6176 - 6176
  • [10] Synthesis of Dense 1,2,3-Triazole Polymers Soluble in Common Organic Solvents
    Yamasaki, Shota
    Kamon, Yuri
    Xu, Linlin
    Hashidzume, Akihito
    POLYMERS, 2021, 13 (10)
12345