Ultrarapid and highly efficient reduction of nitroaromatic compounds using cyclodextrin MOF

被引：27

作者：

Shahzaib, Adnan ^{[1
]}

Shaily ^{[1
]}

Ahmad, Iftkhar ^{[2
]}

Singh, Paramjit ^{[1
]}

Zafar, Fahmina ^{[1
]}

Akhtar, Yasmin ^{[3
]}

Bukhari, Abeer Abdelaziz ^{[3
]}

Nishat, Nahid ^{[1
]}

机构：

[1] Jamia Millia Islamia, Dept Chem, Inorgan Mat Res Lab, New Delhi 110025, India

[2] Jamia Millia Islamia, Dept Chem, Bio Polymer Res Lab, New Delhi 110025, India

[3] Univ Tabuk, Dept Chem, Tabuk 47512, Saudi Arabia

来源：

CATALYSIS COMMUNICATIONS | 2023年 / 174卷

关键词：

Metal-organic frameworks; beta-Cyclodextrin; Photocatalytic reduction; Nitroaromatics compounds; METAL-ORGANIC FRAMEWORKS; PHOTOCATALYTIC REDUCTION; DEGRADATION;

D O I：

10.1016/j.catcom.2022.106569

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein, a metal-organic framework (Cu-beta-CD-MOF) was prepared that incorporates copper (Cu) and beta-cyclodextrin (beta-CD) via vapor diffusion. Cu-beta-CD-MOF was employed as a catalyst for the reduction of various nitroaromatics (NACs) compounds viz. 4-Nitrophenol(4-NP), Nitrobenzene (NB), 2-Nitrophenol(2-NP) and 4-Nitroaniline(4-NA). Cu-beta-CD-MOF was analyzed using diverse techniques, which disclosed a narrow band gap (2.23 eV), enhanced thermal stability, and rod-like crystal morphology. Cu-beta-CD-MOF exhibited high catalytic activity, reducing all NACs in 4 min. As a result of its high photocatalytic efficiency, low cost, non-toxic, and adherence to green chemistry principles, Cu-beta-CD-MOF could be considered for wastewater treatment applications.

引用

页数：11

共 50 条

[41] Palladium-catalyzed reduction of nitroaromatic compounds to the corresponding anilines
Mirza-Aghayan, Maryam
Boukherroub, Rabah
Rahimifard, Mahshid
Bolourtchian, Mohammad
APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (06) : 477 - 480
[42] Catalytic reduction of nitroaromatic compounds by nanoparticle-containing membranes
Dotzauer, David M.
Bruening, Merlin L.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237 : 821 - 821
[43] Nanoparticle-Containing Membranes for the Catalytic Reduction of Nitroaromatic Compounds
Dotzauer, David A.
Bhattacharjee, Somnath
Wen, Ya
Bruening, Merlin L.
LANGMUIR, 2009, 25 (03) : 1865 - 1871
[44] REDUCTION OF NITROAROMATIC COMPOUNDS BY IRON (II) IN AQUEOUS-SOLUTION
FODOR, TC
MACALADY, DL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 224 - CHED
[45] REDUCTION OF NITROAROMATIC COMPOUNDS IN ANAEROBIC SEDIMENT WATER-SYSTEMS
SANDERS, PF
WOLFE, NL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 190 (SEP): : 85 - ENR
[46] Silver nanoparticles stabilized by a polyaminocyclodextrin as catalysts for the reduction of nitroaromatic compounds
Russo, Marco
Armetta, Francesco
Riela, Serena
Martino, Delia Chillura
Lo Meo, Paolo
Noto, Renato
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 408 : 250 - 261
[47] An interpenetrated anionic In(III)-MOF for efficient adsorption/separation of organic dyes and selective sensing of Fe3+ ion and nitroaromatic compounds
Zhang, Hao
Wu, Ji
Geng, Wu-Yue
Luo, Yu-Hui
Ding, Zi-Jun
Wang, Zhi-Xuan
Zhang, Dong-En
JOURNAL OF SOLID STATE CHEMISTRY, 2021, 302
[48] Electrochemical reduction and in-situ electrochemiluminescence detection of nitroaromatic compounds
Ni, Xinyi
Zhao, Yuan
Song, Qijun
ELECTROCHIMICA ACTA, 2015, 164 : 31 - 37
[49] Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light
Xia, Lixin
Hu, Xinhu
Sun, Mengtao
Li, Jushi
Yang, Donghui
Wang, Xiaofang
Xu, Hongxing
JOURNAL OF RAMAN SPECTROSCOPY, 2012, 43 (08) : 1024 - 1028
[50] REDUCTION OF NITROAROMATIC COMPOUNDS IN IRON AND SULFATE-REDUCING ENVIRONMENTS
SCHWARZENBACH, RP
HEIJMAN, CG
HOLLIGER, C
KLAUSEN, J
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 134 - GEOC

← 1 2 3 4 5 →