Effect of particle size on the kinetics of pure oxygen combustion of coke

被引:2
|
作者
Yang, Tao [1 ]
Wei, Bo [1 ]
Wang, Shan [1 ]
Liu, Weihua [1 ]
Chen, Lijuan [1 ]
Wang, Jianjiang [1 ]
Abudureheman, Maierhaba [1 ]
Ma, Jinrong [2 ]
Wang, Feng [2 ]
机构
[1] Xinjiang Univ, Sch Chem Engn & Technol, State Key Lab Chem & Utilizat Carbon Based Energy, Key Lab Coal Clean Convers & Chem Engn Proc, Urumqi 830046, Xinjiang Uygur, Peoples R China
[2] Xinjiang Xinye Energy & Chem Co Ltd, Wujiaqu 831300, Peoples R China
基金
中国国家自然科学基金;
关键词
Coke; Pure oxygen combustion; Heating rate; Particle size; Kinetic parameters; FUEL COMBUSTION; THERMOGRAVIMETRIC ANALYSIS; COAL PROPERTIES; ZHUNDONG COAL; COCOMBUSTION; BEHAVIOR; BIOMASS; GASIFICATION; PYROLYSIS; MINERALS;
D O I
10.1016/j.tca.2022.179405
中图分类号
O414.1 [热力学];
学科分类号
摘要
Non-isothermal thermogravimetry technique was used to analyze three groups of coke samples (S-ZD, M-ZD, and L-ZD) of varying particle sizes. The effect of particle size on kinetic parameters was studied in a pure oxygen atmosphere. The ignition (T-i), peak (T-y), and burnout (T-f) temperatures and the flammability (C) and combustion characteristic (S-n) indexes were determined by varying the heating rate (beta). The activation energy (E-alpha) was evaluated following the Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) methods. T-i, T-p, T-f, C, and S-n correlated positively with the increase in beta in a pure oxygen atmosphere. The order of ignition was L-ZD > M-ZD > S-ZD, and the E-alpha values for the S-ZD, M-ZD, and L-ZD samples were 98.49, 98.35, and 95.17 kJ.mol(-1) (FWO) and 90.32, 90.92, and 89.25 kJ.mol(-1) (KAS), respectively. Particle size exerted little effect on the kinetics of coke combustion.
引用
收藏
页数:11
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